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壳聚糖纤维作为绿色材料去除六价铬离子和铜离子污染物。

A chitosan fiber as green material for removing Cr(VI) ions and Cu(II) ions pollutants.

机构信息

School of Textile Science and Engineering, Tiangong University, Tianjin, 300387, China.

出版信息

Sci Rep. 2021 Nov 25;11(1):22942. doi: 10.1038/s41598-021-02399-5.

Abstract

The application shell uses cellulose as a green and recyclable fiber material, which has great value in the field of water treatment environment. Varying factors, including pH value, dosage of CS, reaction time and original Cr(VI) ions and Cu(II) ions were studied to investigate the Cr(VI) and Cu(II) ions removal efficiency. The obtained shell trichlorocellulose has better permeability to copper ions, which is mainly due to the different oxide states of copper ions and chromium ions in a pH environment, which lead to different combinations. The price of shell cellulose neutralization is relatively low. Metal ions have better absorption properties. The kinetic and thermodynamic characteristics of the adsorption process of copper ions by chitosan yarns were discussed. The adsorption process of copper ions conformed to the quasi-second-order kinetic equation. It can be fitted by Langmuir isotherm. The adsorption of copper ions by the yarn is a spontaneous thermal reaction with both physical adsorption and chemical adsorption. Compared with chromium ions, chitosan fibers have better adsorption of copper ions, which is mainly because the amino groups in chitosan fibers can have good chelation with copper ions. SEM, FTIR, XRD were used to characterize the adsorption of copper ions by chitosan fibers, and the mechanism of the adsorption of metal ions by chitosan fibers was explored.

摘要

应用壳聚糖使用纤维素作为一种绿色可再生纤维材料,在水处理环境领域具有很大的应用价值。研究了不同因素,包括 pH 值、CS 用量、反应时间和原始 Cr(VI)离子和 Cu(II)离子,以研究 Cr(VI)和 Cu(II)离子的去除效率。所得壳聚糖三氯纤维素对铜离子具有更好的渗透性,这主要是由于在 pH 环境下铜离子和铬离子的氧化态不同,导致不同的组合。壳聚糖中和纤维素的价格相对较低。金属离子具有更好的吸收性能。讨论了壳聚糖纤维对铜离子吸附过程的动力学和热力学特性。铜离子的吸附过程符合准二级动力学方程。它可以用 Langmuir 等温线拟合。铜离子的吸附是一种自发的热反应,包括物理吸附和化学吸附。与铬离子相比,壳聚糖纤维对铜离子具有更好的吸附能力,这主要是因为壳聚糖纤维中的氨基可以与铜离子很好地螯合。通过 SEM、FTIR、XRD 对壳聚糖纤维吸附铜离子进行了表征,探讨了壳聚糖纤维吸附金属离子的机理。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9dc3/8617153/3204a257e1b6/41598_2021_2399_Fig1_HTML.jpg

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