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沿水流路径的水文地球化学反应对恒河地下水砷和锰分布及动态的对比影响

Influence of hydrogeochemical reactions along flow paths on contrasting groundwater arsenic and manganese distribution and dynamics across the Ganges River.

机构信息

Department of Geology and Geophysics, Indian Institute of Technology Kharagpur, Kharagpur, India.

Department of Geology and Geophysics, Indian Institute of Technology Kharagpur, Kharagpur, India; School of Environmental Science and Engineering, Indian Institute of Technology Kharagpur, Kharagpur, India; Applied Policy Advisory to Hydrogeosciences Group, Indian Institute of Technology Kharagpur, Kharagpur, India.

出版信息

Chemosphere. 2022 Jan;287(Pt 2):132144. doi: 10.1016/j.chemosphere.2021.132144. Epub 2021 Sep 3.

DOI:10.1016/j.chemosphere.2021.132144
PMID:34826895
Abstract

The groundwater within the aquifers of the Ganges River delta exhibits significant spatial variability in concentrations of redox-sensitive solutes [e.g., arsenic (As), iron (Fe), manganese (Mn)]. The groundwater As and Mn concentrations show conspicuous contrasting distribution on the opposite banks of the Bhagirathi-Hooghly (B-H) River, the Indian distributary of the Ganges River. Here, we investigate the differences in hydrostratigraphic framework and groundwater evolutionary pathways across the B-H River that might have resulted in such variations. We developed a hydrostratigraphic model for the region and also used inverse reaction-path modeling along three hypothesized end-member flow paths to understand the dominant processes that might control As and Mn cycling within the aquifers. Our results indicate that the variability of As and Mn across the B-H River is a function of a complex interplay between the aquifer architecture, groundwater chemistry, and redox conditions.

摘要

恒河三角洲含水层中的地下水在氧化还原敏感溶质(如砷 (As)、铁 (Fe)、锰 (Mn))浓度方面表现出显著的空间变异性。恒河印度支流帕德玛河与胡格利河(B-H 河)两岸的地下水 As 和 Mn 浓度分布存在明显差异。在这里,我们研究了 B-H 河两岸的水文地层结构和地下水演化途径的差异,这些差异可能导致了这种变化。我们为该地区开发了一个水文地层模型,并沿三条假设的端元流动路径使用反反应路径建模,以了解控制含水层中 As 和 Mn 循环的主要过程。我们的结果表明,B-H 河两岸的 As 和 Mn 变化是含水层结构、地下水化学和氧化还原条件之间复杂相互作用的结果。

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