Arahman Nasrul, Rosnelly Cut Meurah, Windana Diki Sukma, Fahrina Afrillia, Silmina Silmina, Maimun Teuku, Mulyati Sri, Fathanah Umi, Aprilia Sri, Bilad Muhammad Roil, Gunawan Poernomo, Dzulhijjah Wafiq Alni, Halimah Nur
Department of Chemical Engineering, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia.
Magister Program of Environmental Management, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia.
Polymers (Basel). 2021 Nov 9;13(22):3872. doi: 10.3390/polym13223872.
Membrane properties are highly affected by the composition of the polymer solutions that make up the membrane material and their influence in the filtration performance on the separation or purification process. This paper studies the effects of the addition of pluronic (Plu) and patchouli oil (PO) in a polyethersulfone (PES) solution on the membrane morphology, membrane hydrophilicity, and filtration performance in the pesticide removal compound in the water sample. Three types of membranes with the composition of PES, PES + Plu, and PES + Plu + patchouli oil were prepared through a polymer phase inversion technique in an aqueous solvent. The resulting membranes were then analyzed and tested for their mechanical properties, hydrophilicity, antimicrobial properties, and filtration performance (cross-flow ultrafiltration). The results show that all of the prepared membranes could reject 75% of the pesticide. The modification of the PES membrane with Plu was shown to increase the overall pore size by altering the pore morphology of the pristine PES, which eventually increased the permeation flux of the ultrafiltration process. Furthermore, patchouli oil added antimicrobial properties, potentially minimizing the biofilm formation on the membrane surface.
膜的性能受到构成膜材料的聚合物溶液组成的高度影响,以及它们对分离或纯化过程中过滤性能的影响。本文研究了在聚醚砜(PES)溶液中添加普朗尼克(Plu)和广藿香油(PO)对膜形态、膜亲水性以及水样中农药去除化合物过滤性能的影响。通过在水性溶剂中采用聚合物相转化技术制备了三种膜,其组成分别为PES、PES + Plu和PES + Plu + 广藿香油。然后对所得膜进行分析和测试,考察其机械性能、亲水性、抗菌性能和过滤性能(错流超滤)。结果表明,所有制备的膜都能截留75%的农药。用Plu对PES膜进行改性可通过改变原始PES的孔形态来增加整体孔径,最终提高超滤过程的渗透通量。此外,广藿香油具有抗菌性能,可能会减少膜表面生物膜的形成。