Serra-Parareda Ferran, Vilaseca Fabiola, Aguado Roberto, Espinach Francesc X, Tarrés Quim, Delgado-Aguilar Marc
LEPAMAP-PRODIS Research Group, University of Girona, C/Maria Aurèlia Capmany 61, 17003 Girona, Spain.
Advanced Biomaterials and Nanotechnology, Department of Chemical Engineering, University of Girona, Maria Aurèlia Capmany 61, 17003 Girona, Spain.
Polymers (Basel). 2021 Nov 15;13(22):3947. doi: 10.3390/polym13223947.
In this study, Young's modulus of henequen fibers was estimated through micromechanical modeling of polypropylene (PP)-based composites, and further corroborated through a single filament tensile test after applying a correction method. PP and henequen strands, chopped to 1 mm length, were mixed in the presence of maleic anhydride grafted polypropylene (MAPP). A 4 wt.% of MAPP showed an effective enhancement of the interfacial adhesion. The composites were mold-injected into dog-bone specimens and tensile tested. The Young's modulus of the composites increased steadily and linearly up to 50 wt.% of fiber content from 1.5 to 6.4 GPa, corresponding to a 327% increase. Certainly, henequen fibers showed a comparable stiffening capacity of PP composites than glass fibers. The intrinsic Young's modulus of the fibers was predicted through well established models such as Hirsch or Tsai-Pagano, yielding average values of 30.5 and 34.6 GPa, respectively. The single filament test performed to henequen strands resulted in values between 16 and 27 GPa depending on the gauge length, although, after applying a correction method, a Young's modulus of 33.3 GPa was obtained. Overall, the present work presents the great potential for henequen fibers as PP reinforcement. Moreover, relationships between micromechanics models and filament testing to estimate Young's modulus of the fibers were explored.
在本研究中,通过对聚丙烯(PP)基复合材料进行微观力学建模来估算henequen纤维的杨氏模量,并在应用校正方法后通过单丝拉伸试验进一步证实。将切碎至1毫米长的PP和henequen股线在马来酸酐接枝聚丙烯(MAPP)存在下混合。4 wt.%的MAPP显示出界面粘附力的有效增强。将复合材料注塑成狗骨形试样并进行拉伸试验。复合材料的杨氏模量在纤维含量达到50 wt.%之前从1.5 GPa稳步线性增加到6.4 GPa,增幅达327%。当然,henequen纤维对PP复合材料的增强能力与玻璃纤维相当。通过Hirsch或Tsai-Pagano等成熟模型预测纤维的本征杨氏模量,其平均值分别为30.5 GPa和34.6 GPa。对henequen股线进行的单丝试验根据标距长度得出的值在16至27 GPa之间,不过,在应用校正方法后,得到的杨氏模量为33.3 GPa。总体而言,本研究表明henequen纤维作为PP增强材料具有巨大潜力。此外,还探索了微观力学模型与细丝测试之间的关系,以估算纤维的杨氏模量。