Zhang Yangan, Li Yao, Yuan Xueguang, Yan Xin, Zhang Xia
State Key Laboratory of Information Photonics and Optical Communications, Beijing University of Posts and Telecommunications, Beijing 100876, China.
Nanomaterials (Basel). 2021 Oct 22;11(11):2807. doi: 10.3390/nano11112807.
A laterally oriented GaAs p-i-n nanowire solar cell with Ag gratings is proposed and studied via coupled three-dimensional optoelectronic simulations. The results show that the gratings significantly enhance the absorption of nanowire for both TM and TE polarized light due to the combined effect of grating diffraction, excitation of plasmon polaritons, and suppression of carrier recombination. At an optimal grating period, the absorption at 650-800 nm, which is an absorption trough for pure nanowire, is substantially enhanced, raising the conversion efficiency from 8.7% to 14.7%. Moreover, the gratings enhance the weak absorption at long wavelengths and extend the absorption cutoff wavelength for ultrathin nanowires, yielding a remarkable efficiency of 13.3% for the NW with a small diameter of 90 nm, 2.6 times that without gratings. This work may pave the way toward the development of ultrathin high-efficiency nanoscale solar cells.
提出了一种带有银光栅的横向取向砷化镓p-i-n纳米线太阳能电池,并通过三维光电耦合模拟进行了研究。结果表明,由于光栅衍射、表面等离激元极化激元的激发以及载流子复合的抑制等综合效应,光栅显著增强了纳米线对TM和TE偏振光的吸收。在最佳光栅周期下,650 - 800nm处(这是纯纳米线的吸收低谷)的吸收得到大幅增强,使转换效率从8.7%提高到14.7%。此外,光栅增强了长波长处的弱吸收,并延长了超薄纳米线的吸收截止波长,对于直径仅为90nm的纳米线,效率显著提高到13.3%,是没有光栅时的2.6倍。这项工作可能为超薄高效纳米级太阳能电池的发展铺平道路。