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多功能导电铜电镀织物通过原位沉积铜和银纳米颗粒实现敏化。

Multifunctional Electrically Conductive Copper Electroplated Fabrics Sensitizes by In-Situ Deposition of Copper and Silver Nanoparticles.

作者信息

Ali Azam, Hussain Fiaz, Kalsoom Ambreen, Riaz Tauqeer, Zaman Khan Muhammad, Zubair Zakariya, Shaker Khubab, Militky Jiri, Noman Muhammad Tayyab, Ashraf Munir

机构信息

Department of Materials and Textile Engineering, Technical University of Liberec, 46015 Liberec, Czech Republic.

Functional Textile Research Group, Faculty of Engineering and Technology, National Textile University, Faisalabad 37610, Pakistan.

出版信息

Nanomaterials (Basel). 2021 Nov 16;11(11):3097. doi: 10.3390/nano11113097.

Abstract

In this study, we developed multifunctional and durable textile sensors. The fabrics were coated with metal in two steps. At first, pretreatment of fabric was performed, and then copper and silver particles were coated by the chemical reduction method. Hence, the absorbance/adherence of metal was confirmed by the deposition of particles on microfibers. The particles filled the micro spaces between the fibers and made the continuous network to facilitate the electrical conduction. Secondly, further electroplating of the metal was performed to make the compact layer on the particle- coated fabric. The fabrics were analyzed against electrical resistivity and electromagnetic shielding over the frequency range of 200 MHz to 1500 MHz. The presence of metal coating was confirmed from the surface microstructure of coated fabric samples examined by scanning electron microscopy, EDS, and XRD tests. For optimized plating parameters, the minimum surface resistivity of 67 Ω, EMI shielding of 66 dB and Ohmic heating of 118 °C at 10 V was observed. It was found that EMI SH was increased with an increase in the deposition rate of the metal. Furthermore, towards the end, the durability of conductive textiles was observed against severe washing. It was observed that even after severe washing there was an insignificant increase in electrical resistivity and good retention of the metal coating, as was also proven with SEM images.

摘要

在本研究中,我们开发了多功能且耐用的纺织传感器。织物分两步进行金属涂层处理。首先,对织物进行预处理,然后通过化学还原法涂覆铜和银颗粒。因此,通过颗粒在微纤维上的沉积证实了金属的吸收/附着。颗粒填充了纤维之间的微小间隙并形成连续网络以促进导电。其次,对金属进行进一步电镀,以便在颗粒涂覆的织物上形成致密层。对织物在200 MHz至1500 MHz频率范围内的电阻率和电磁屏蔽进行了分析。通过扫描电子显微镜、能谱分析和X射线衍射测试对涂覆织物样品的表面微观结构进行检查,证实了金属涂层的存在。对于优化的电镀参数,观察到最小表面电阻率为67Ω,电磁干扰屏蔽为66 dB,在10 V电压下欧姆加热为118°C。发现电磁干扰屏蔽随着金属沉积速率的增加而提高。此外,最后观察了导电纺织品在剧烈洗涤下的耐久性。观察到即使经过剧烈洗涤,电阻率的增加也不显著,并且金属涂层保持良好,扫描电子显微镜图像也证明了这一点。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0571/8623616/d785888c5d86/nanomaterials-11-03097-g002.jpg

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