Electrochemically enhanced adsorption of organic dyes from aqueous using a freestanding metal-organic frameworks/cellulose-derived porous monolithic carbon foam.

Monolithic carbon foams are promising materials for adsorption due to the easy recyclability and without secondary-pollution. However, poor adsorption efficiency for organic pollutants limits its practical application. Hence, this work proposed a novel monolithic porous carbon foam by a facile carbonization approach as freestanding electrodes to remove the organic dyes. The prepared carbon foam derived from waste cigarette filters and zeolitic-imidazolate frameworks-8 with well-developed pores, and the calculated surface area is 1457 m·g, and exhibited an outstanding removal efficiency for methylene blue in aqueous. The maximum adsorption capacity for methylene blue can reach up to 1846.7 mg·g under the applied voltage of -1.2 V. Importantly, as-prepared carbon foams possessed excellent stability, and the removal efficiency can remain above 85% after 5 cycles. Thus, obtained porous carbon foams in this paper as a free standing electrode is expected to be promising materials of adsorbent besides supercapacitors.