Zhu Yixuan, Tan Zhibing, Hong Wenjing
State Key Laboratory of Physical Chemistry of Solid Surfaces, iChEM, NEL, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
ACS Omega. 2021 Nov 12;6(46):30873-30888. doi: 10.1021/acsomega.1c04785. eCollection 2021 Nov 23.
The fabrication and characterization of single-molecule junctions provide a unique platform to study the physical phenomena of a single molecule, and the electrical characterization enables us to understand the electrical transport properties of a single molecule and guide the fabrication of molecular electronic devices. However, the electrical characterization of single-molecule junctions is sometimes insufficient to extract the structural information on single-molecule junctions, and an alternate method to address this problem is to characterize the mechanical properties of single-molecule junctions. Simultaneous measurement of mechanical and electrical properties can provide complementary information on single molecules to analyze the correlations of their electrical and mechanical properties in the evolution of single-molecule junctions. In this mini-review, we summarize the progress on the simultaneous characterizations of mechanical and electrical properties for single-molecule junctions, and discuss the challenges and perspectives of this research area.
单分子结的制备与表征为研究单分子的物理现象提供了一个独特的平台,而电学表征使我们能够了解单分子的电输运性质,并指导分子电子器件的制备。然而,单分子结的电学表征有时不足以提取单分子结的结构信息,解决这一问题的另一种方法是表征单分子结的力学性质。同时测量力学和电学性质可以提供关于单分子的互补信息,以分析它们在单分子结演化过程中的电学和力学性质的相关性。在本综述中,我们总结了单分子结力学和电学性质同时表征的研究进展,并讨论了该研究领域的挑战和前景。