KU-KIST Graduate School of Converging Science and Technology, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Republic of Korea.
Biomedical Engineering Research Center, Samsung Medical Center, Sungkyunkwan University School of Medicine, 81, Irwon-ro, Gangnam-gu, Seoul 06351, Republic of Korea.
ACS Nano. 2021 Dec 28;15(12):19310-19320. doi: 10.1021/acsnano.1c05463. Epub 2021 Nov 29.
The lifetime of transient electronic components can be programmed via the use of encapsulation/passivation layers or of on-demand, stimuli-responsive polymers (heat, light, or chemicals), but yet most research is limited to slow dissolution rate, hazardous constituents, or byproducts, or complicated synthesis of reactants. Here we present a physicochemical destruction system with dissolvable, nontoxic materials as an efficient, multipurpose platform, where chemically produced bubbles rapidly collapse device structures and acidic molecules accelerate dissolution of functional traces. Extensive studies of composites based on biodegradable polymers (gelatin and poly(lactic--glycolic acid)) and harmless blowing agents (organic acid and bicarbonate salt) validate the capability for the desired system. Integration with wearable/recyclable electronic components, fast-degradable device layouts, and wireless microfluidic devices highlights potential applicability toward versatile/multifunctional transient systems. toxicity tests demonstrate biological safety of the proposed system.
通过使用封装/钝化层或按需、响应性聚合物(热、光或化学物质),可以对瞬态电子元件的寿命进行编程,但大多数研究都限于缓慢的溶解速率、有害物质成分或副产物,或者反应物的复杂合成。在这里,我们提出了一种具有可溶解、无毒材料的物理化学破坏系统,作为一种高效、多用途的平台,其中化学产生的气泡会迅速破坏器件结构,而酸性分子会加速功能痕迹的溶解。对基于可生物降解聚合物(明胶和聚(乳酸- - 乙醇酸))和无害发泡剂(有机酸和碳酸氢盐)的复合材料进行了广泛研究,验证了所需系统的能力。与可穿戴/可回收电子元件的集成、快速降解的器件布局和无线微流控器件突出了向多功能/多用途瞬态系统应用的潜力。毒性测试证明了所提出的系统具有生物安全性。