Ding Bingbing, Ma Xiang
Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China.
Langmuir. 2021 Dec 14;37(49):14229-14236. doi: 10.1021/acs.langmuir.1c02612. Epub 2021 Nov 30.
Eye-catching organic room-temperature phosphorescence (RTP) is becoming more and more universal through various strategies, such as crystal engineering, macrocyclic inclusion, host-guest doping, and copolymerization. It is always the pursuit of researchers to prepare high-efficiency RTP materials by the simplest strategy. The doping strategy is one of the most simple and effective strategies and involves mixing phosphor with rigid host material. The principle of the doping RTP system has developed from a conventional rigidity effect of the host through the host-guest interaction. This perspective aims at multifunctional host materials and summarizes the recent development of doping organic RTP systems. Doping systems play more and more important roles in the development of long-afterglow and high-yield RTP materials. The application scenarios of RTP are becoming wider and wider.
通过晶体工程、大环包合、主客体掺杂和共聚等各种策略,引人注目的有机室温磷光(RTP)正变得越来越普遍。采用最简单的策略制备高效RTP材料一直是研究人员追求的目标。掺杂策略是最简单有效的策略之一,涉及将磷光体与刚性主体材料混合。掺杂RTP体系的原理已从主体的传统刚性效应通过主客体相互作用发展而来。本综述针对多功能主体材料,总结了掺杂有机RTP体系的最新进展。掺杂体系在长余辉和高产率RTP材料的发展中发挥着越来越重要的作用。RTP的应用场景正变得越来越广泛。