Müller Carolin, Friedländer Ilse, Bagemihl Benedikt, Rau Sven, Dietzek-Ivanšić Benjamin
Friedrich Schiller University Jena, Institute of Physical Chemistry, Helmholtzweg 4, 07743, Jena, Germany.
Leibniz Institute of Photonic Technology, Research Department Functional Interfaces, Albert-Einstein-Str. 9, 07745, Jena, Germany.
Phys Chem Chem Phys. 2021 Dec 15;23(48):27397-27403. doi: 10.1039/d1cp04498b.
spectroelectrochemical studies focussing on the Franck-Condon region and sub-ns electron transfer processes in Ru(II)-tpphz-Pt(II) based photocatalysts reveal that single-electron reduction effectively hinders intramolecular electron transfer between the photoexcited Ru chromophore and the Pt center.
聚焦于基于钌（II）-四吡啶并菲咯嗪-铂（II）的光催化剂中弗兰克-康登区域和亚纳秒级电子转移过程的光谱电化学研究表明，单电子还原有效地阻碍了光激发的钌发色团与铂中心之间的分子内电子转移。
