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用于氢解反应的负载在活性生物炭上的钯-氧化铝催化剂的表征数据

Characterization data of palladium-alumina on activated biochar catalyst for hydrogenolysis reactions.

作者信息

Gurrala Lakshmiprasad, Kumar M Midhun, Paek Changyub, Vinu R

机构信息

Department of Chemical Engineering and National Center for Combustion Research and Development, Indian Institute of Technology Madras, Chennai 600036, India.

Corporate Strategic Research, ExxonMobil Research and Engineering, Annandale, NJ 08801, United States.

出版信息

Data Brief. 2021 Nov 19;39:107591. doi: 10.1016/j.dib.2021.107591. eCollection 2021 Dec.

Abstract

This article presents experimental data on the techniques used for the characterization of Pd-AlO supported on activated biochar (2Pd-5Al/ABC) catalyst. The reported data is collected as a part of the research on the 2Pd-5Al/ABC catalyst used for lignin hydrogenolysis [1]. The data on X-ray powder diffraction, ammonia-temperature programmed desorption, pyridine diffuse reflectance infrared Fourier transform spectroscopy, and high-resolution scanning electron microscopy of various catalysts are valuable to study the changes in surface morphology and acidity upon metal loading. The data from thermogravimetric analysis, X-ray photoelectron spectroscopy, and scanning electron microscopy-energy dispersive X-ray spectroscopy are also provided to understand the thermal stability, ionic state of various metals and elemental composition of the catalyst, respectively. The data provided can be used for developing novel catalysts from renewable biochar, and the characterization of noble metal-metal oxide loaded catalysts can aid researchers to design composite catalytic materials for various applications.

摘要

本文介绍了用于表征负载在活性生物炭上的钯-氧化铝(2Pd-5Al/ABC)催化剂的技术的实验数据。所报告的数据是作为对用于木质素氢解的2Pd-5Al/ABC催化剂的研究的一部分收集的[1]。各种催化剂的X射线粉末衍射、氨程序升温脱附、吡啶漫反射红外傅里叶变换光谱和高分辨率扫描电子显微镜数据对于研究金属负载后表面形态和酸度的变化很有价值。还提供了热重分析、X射线光电子能谱和扫描电子显微镜-能量色散X射线光谱的数据,分别用于了解催化剂的热稳定性、各种金属的离子状态和元素组成。所提供的数据可用于从可再生生物炭开发新型催化剂,负载贵金属-金属氧化物催化剂的表征可帮助研究人员设计用于各种应用的复合催化材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4133/8626653/5c9c7346fbbd/gr1.jpg

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