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典型电子废弃物拆解活动产生的空气多污染物污染特征及风险评估

Pollution characteristics and risk assessment of air multi-pollutants from typical e-waste dismantling activities.

作者信息

Wang Hailin, Hao Run, Nie Lei, Zhang Xin, Zhang Yuanxun

机构信息

Beijing Key Laboratory for VOCs Pollution Prevention and Treatment Technology Application, Beijing Municipal Research Institute of Environment Protection, Beijing, 100037, China.

College of Resources and Environment, University of Chinese Academy of Sciences, Beijing, 101408, China; Yanshan Earth Critical Zone and Surface Fluxes Research Station, University of Chinese Academy of Sciences, Beijing, 101408, China.

出版信息

Environ Pollut. 2022 Feb 1;294:118630. doi: 10.1016/j.envpol.2021.118630. Epub 2021 Dec 4.

Abstract

This study investigated the characteristics of air multi-pollutants emitted during typical electronic waste (e-waste) dismantling processes and assessed their risks to the environment and human health. Concentrations of total volatile organic compounds (TVOCs), polybrominated diphenyl ethers (PBDEs), and polycyclic aromatic hydrocarbons (PAHs) in a typical e-waste dismantling workshop were 137 μg/m, 135 ng/m and 42 ng/m, respectively, which were lower than those without emission control measures. The partial removal of pollutants due to the emission control measures also decreased the ozone formation potential and non-cancer risk of volatile organic compounds (VOCs). In the workshop, the lifetime cancer risk (LCR) of VOCs (8.1 × 10) was close to the recommended values. Conversely, the LCR of PAHs (3.6 × 10) and the total exposure index of PBDEs (19 ng/d) were remarkably lower than the recommended values of 10 and that without emission control measures, respectively. Meanwhile, the concentrations of TVOCs, polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs), PBDEs, and PAHs in the outlet were approximately 10-30 times higher than those in the workshop. In addition, the LCR of TVOCs within a 5-km radius area remained higher than the accepted value (10), and the inhalation exposure risk of PCDD/Fs within a 20-km radius area was five times higher than the recommended value. Therefore, the emissions from e-waste recycling processes should be considered as an important source of air pollution, and more efficient control measures should be taken in the future.

摘要

本研究调查了典型电子废物(电子垃圾)拆解过程中排放的空气多污染物特征,并评估了它们对环境和人类健康的风险。典型电子废物拆解车间中总挥发性有机化合物(TVOCs)、多溴二苯醚(PBDEs)和多环芳烃(PAHs)的浓度分别为137μg/m、135ng/m和42ng/m,低于无排放控制措施时的浓度。排放控制措施对污染物的部分去除也降低了挥发性有机化合物(VOCs)的臭氧生成潜力和非致癌风险。在该车间,VOCs的终生癌症风险(LCR)为8.1×10,接近推荐值。相反,PAHs的LCR(3.6×10)和PBDEs的总暴露指数(19ng/d)分别显著低于推荐值10和无排放控制措施时的值。同时,出口处TVOCs、多氯二苯并对二恶英/呋喃(PCDD/Fs)、PBDEs和PAHs的浓度比车间内高约10 - 30倍。此外,5公里半径区域内TVOCs的LCR仍高于可接受值(10),20公里半径区域内PCDD/Fs的吸入暴露风险比推荐值高五倍。因此,电子废物回收过程的排放应被视为空气污染的一个重要来源,未来应采取更有效的控制措施。

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