Interfacial Engineering of Metal/Metal Oxide Heterojunctions toward Oxygen Reduction and Evolution Reactions.

Oxygen reduction reactions (ORR) and oxygen evolution reactions (OER) are two very important electrochemical processes for renewable energy conversion and storage devices. Electrocatalysts are needed to accelerate their sluggish kinetics to improve energy conversion efficiencies. Hence, extensive efforts have been devoted to the development of OER and ORR electrocatalysts with high activity and stability as well as low cost. Among these developed electrocatalysts, metal/metal oxide heterostructures attract a great deal of research interest because their catalytic performances can be tuned by interface engineering. In this Review, the latest achievements in interface engineering of metal/metal oxides heterostructures toward ORR and OER are described. The effects of the metal/metal oxide interface on catalysis are first discussed. Then, the approaches for interface engineering are illustrated. The developments of interface engineering in OER and ORR catalysis as well as bifunctional electrocatalysis are further introduced. Lastly, a perspective for future development of interface engineering in metal/metal oxide for OER and ORR is discussed.