Xiang Jing, Peng Min, Pan Yi, Luo Li-Juan, Cheng Shun-Cheung, Jin Xin-Xin, Yiu Shek-Man, Man Wai-Lun, Ko Chi-Chiu, Lau Kai-Chung, Lau Tai-Chu
College of Chemistry and Environmental Engineering, Yangtze University Jingzhou 434020 Hubei P. R. China
Department of Chemistry, City University of Hong Kong Tat Chee Avenue Kowloon Tong Hong Kong China
Chem Sci. 2021 Oct 9;12(43):14494-14498. doi: 10.1039/d1sc04369b. eCollection 2021 Nov 10.
-Dealkylation of amines by metal oxo intermediates (M[double bond, length as m-dash]O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of -dealkylation of various alkylamines by a luminescent osmium(vi) nitrido complex induced by visible light.
金属氧代中间体（M=O）对胺类的脱烷基作用与生物系统中的药物解毒和DNA修复有关。在本研究中，我们报道了首例由可见光诱导的发光锇（VI）氮化物配合物对各种烷基胺进行脱烷基作用的实例。
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