Hesari Mahdi, Ma Hui, Ding Zhifeng
Department of Chemistry, The University of Western Ontario London Ontario N6A 5B7 Canada
State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University Nanjing 210023 China
Chem Sci. 2021 Oct 7;12(43):14540-14545. doi: 10.1039/d1sc04018a. eCollection 2021 Nov 10.
Herein, we report for the first time single Au nanocluster reaction events of highly efficient electrochemiluminescence (ECL) with tri--propylamine radicals as a reductive co-reactant at the surface of an ultramicroelectrode (UME). The statistical analyses of individual reactions confirm stochastic single ones influenced by the applied potential.
在此，我们首次报道了在超微电极（UME）表面以三丙胺自由基作为还原共反应物的高效电化学发光（ECL）的单个金纳米簇反应事件。对单个反应的统计分析证实了受施加电位影响的随机单反应。
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