分子催化剂的分区用于非正交串联催化。
Compartmentalisation of molecular catalysts for nonorthogonal tandem catalysis.
机构信息
Molecular Design Institute and Department of Chemistry, New York University, 100 Washington Square East New York, NY 10003, USA.
School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA 30332-0100, USA.
出版信息
Chem Soc Rev. 2022 Jan 4;51(1):57-70. doi: 10.1039/d1cs00530h.
The development of nonorthogonal tandem catalysis enables the use of a combination of arbitrary catalysts to rapidly synthesize complex products in a substainable, efficient, and timely manner. The key is to compartmentalise the molecular catalysts, thereby overcoming inherent incompatibilities between individual catalysts or reaction conditions. This tutorial review analyses the development of the past two decades in the field of nonorthogonal tandem catalysis with an emphasis on compartmentalisation strategies. We highlight design principles of functional materials for compartmentalisation and suggest future directions in the field of nonorthogonal tandem catalysis.
非正交串联催化的发展使得可以使用任意组合的催化剂来快速、可持续、高效且及时地合成复杂产物。关键是将分子催化剂分隔开，从而克服单个催化剂或反应条件之间固有的不兼容性。本综述分析了过去二十年来非正交串联催化领域的发展，重点介绍了分隔策略。我们强调了用于分隔的功能材料的设计原则，并对非正交串联催化领域的未来方向提出了建议。
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