CARTIF Technology Centre, Boecillo, Valladolid, 47151, Spain.
Chemosphere. 2022 Feb;289:133165. doi: 10.1016/j.chemosphere.2021.133165. Epub 2021 Dec 6.
When dealing with lignocellulosic biomass in anaerobic digestion, a pretreatment stage is always required to open the structure of the material, facilitating its degradation. Numerous methods have been developed to pretreat lignocellulosic biomass. Four of them: cavitation, pelleting, extrusion and torrefaction have been comparatively studied in this paper as ways to improve the production of methane by anaerobic digestion of two different feedstocks: barley straw and vine shoots. Additionally, how the selected pretreatments and the nature of the feedstock influence the formation of individual volatile fatty acids was examined. Cavitation was revealed as the most efficient pretreatment, increasing 240% and 360% the methane production for barley straw and vine shoots, respectively, although in absolute terms, barley straw has higher production rate and yield than vine shoots. Torrefaction carried out at 180 °C increased methane production, 81% for straw and 25% for vine shoots, while the process at higher temperatures (220 °C) negatively affected biogas production from both feedstocks. Finally, volatile fatty acids accumulation seems to neutralize any potential positive effects of densification pretreatments.
在厌氧消化处理木质纤维素生物质时,通常需要预处理阶段来打开物料的结构,使其易于降解。已经开发了许多方法来预处理木质纤维素生物质。本文比较研究了其中四种方法:空化、制粒、挤压和热解,以提高两种不同原料(大麦秸秆和葡萄藤)的厌氧消化生产甲烷的产量。此外,还研究了所选预处理方法和原料性质如何影响各挥发性脂肪酸的形成。空化被证明是最有效的预处理方法,分别使大麦秸秆和葡萄藤的甲烷产量增加了 240%和 360%,尽管就绝对值而言,大麦秸秆的生产速率和产量均高于葡萄藤。在 180°C 下进行的热解使稻草的甲烷产量增加了 81%,而使葡萄藤的甲烷产量增加了 25%,而在更高温度(220°C)下进行的热解则对两种原料的沼气产量产生了负面影响。最后,挥发性脂肪酸的积累似乎抵消了致密化预处理的任何潜在积极影响。