Zheng Xinchao, Liu Fang, Luo Tao, Duan Yanfu, Yi Yu, Hua Cheng
School of Civil Engineering, Xijing University, Xi'an 710123, China.
Shaanxi Key Laboratory of Safety and Durability of Concrete Structures, Xi'an 710123, China.
Materials (Basel). 2021 Nov 26;14(23):7228. doi: 10.3390/ma14237228.
The macroscopic mechanical properties and frost resistance durability of concrete are closely related to the changes in the internal pore structure. In this study, the two-dimensional and three-dimensional ICT (Industrial Computerized Tomography) pore characteristics of C30 concrete specimens before and after freezing and thawing in clean water, 5 wt.% NaCl, 5 wt.% CaCl, and 5 wt.% CHCOOK solution environments are obtained through concrete frost resistance durability test and ICT scanning technology. The effects of pore structure changes on concrete frost resistance, durability, and compressive strength mechanical properties after freezing and thawing cycles in different salt solution environments are analyzed. This paper provides new means and ideas for the study of concrete pores. The results show that with the increase in the freezing and thawing times, the concrete porosity, two-dimensional pore area, three-dimensional pore volume, and pore number generally increase in any solution environment, resulting in the loss of concrete compressive strength, mortar spalling, and the decrease in the relative dynamic elastic modulus. Among them, the CHCOOK solution has the least influence on the concrete pore changes; the NaCl solution has the greatest influence on the change in the concrete internal porosity. The damage of CaCl solution to concrete is second only to the NaCl solution, followed by clean water. The increase in the concrete internal porosity from high to low is NaCl, CaCl, clean water, and CHCOOK. The change in the pore volume of 0.1 to 1 mm after the freeze-thaw cycle is the main factor for reducing concrete strength. The test results have certain guiding value for the selection of deicing salt in engineering.
混凝土的宏观力学性能和抗冻耐久性与内部孔隙结构的变化密切相关。本研究通过混凝土抗冻耐久性试验和工业计算机断层扫描(ICT)技术,获取了C30混凝土试件在清水、5 wt.% NaCl、5 wt.% CaCl和5 wt.% CHCOOK溶液环境中冻融前后的二维和三维ICT孔隙特征。分析了不同盐溶液环境下冻融循环后孔隙结构变化对混凝土抗冻性、耐久性和抗压强度力学性能的影响。本文为混凝土孔隙研究提供了新的手段和思路。结果表明,随着冻融次数的增加,在任何溶液环境下混凝土的孔隙率、二维孔隙面积、三维孔隙体积和孔隙数量普遍增加,导致混凝土抗压强度损失、砂浆剥落以及相对动弹模量降低。其中,CHCOOK溶液对混凝土孔隙变化的影响最小;NaCl溶液对混凝土内部孔隙率变化的影响最大。CaCl溶液对混凝土的损伤仅次于NaCl溶液,其次是清水。混凝土内部孔隙率从高到低的增加顺序为NaCl、CaCl、清水、CHCOOK。冻融循环后0.1至1 mm孔隙体积的变化是降低混凝土强度的主要因素。试验结果对工程中除冰盐的选择具有一定的指导价值。