可见光诱导光催化剂催化选择性卤化反应。
Visible-Light-Induced Catalytic Selective Halogenation with Photocatalyst.
机构信息
Department of Nuclear Medicine, Molecular Imaging & Therapeutic Medicine Research Center, Jeonbuk National University Medical School and Hospital, Jeonju 54907, Korea.
Research Institute of Clinical Medicine of Jeonbuk National University, Biomedical Research Institute of Jeonbuk National University Hospital, Jeonju 54907, Korea.
出版信息
Molecules. 2021 Dec 5;26(23):7380. doi: 10.3390/molecules26237380.
Halide moieties are essential structures of compounds in organic chemistry due to their popularity and wide applications in many fields such as natural compounds, agrochemicals, and pharmaceuticals. Thus, many methods have been developed to introduce halides into various organic molecules. Recently, visible-light-driven reactions have emerged as useful methods of organic synthesis. Particularly, halogenation strategies using visible light have significantly improved the reaction efficiency and reduced toxicity, as well as promoted reactions under mild conditions. In this review, we have summarized recent studies in visible-light-mediated halogenation (chlorination, bromination, and iodination) with photocatalysts.
卤化物是有机化学化合物的重要结构，因为它们在许多领域（如天然化合物、农用化学品和药物）中的普及和广泛应用。因此，已经开发出许多方法将卤化物引入各种有机分子中。最近，可见光驱动的反应已成为有机合成的有用方法。特别是，使用可见光的卤化策略显著提高了反应效率，降低了毒性，并促进了温和条件下的反应。在这篇综述中，我们总结了最近使用光催化剂进行的可见光介导的卤化（氯化、溴化和碘化）研究。
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