Yue Erlin, Dettling Lea, Sklorz Julian A W, Kaiser Selina, Weber Manuela, Müller Christian
Freie Universität Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34/36, Berlin 14195, Germany.
Shaanxi Key Laboratory of Chemical Reaction Engineering, Key Laboratory of New Energy & New Functional Materials, College of Chemistry and Chemical Engineering, Yan'an University, Yan'an, Shaanxi 716000, People's Republic of China.
Chem Commun (Camb). 2021 Dec 23;58(2):310-313. doi: 10.1039/d1cc06205k.
Novel tosyl- and mesitylsulfonyl-substituted triazaphospholes were synthesized and structurally characterized. In an attempt to prepare the corresponding Au(I)-complexes with stoichiometric amounts of AuCl·S(CH), -1,3-diphospha(III)-2,4-diazane-AuCl-complexes were obtained instead. Our here presented results offer a new strategy for preparing such coordination compounds selectively in a one-pot approach.
合成了新型甲苯磺酰基和均三甲苯磺酰基取代的三氮杂磷环戊二烯，并对其结构进行了表征。在尝试用化学计量的AuCl·S(CH)制备相应的Au(I)配合物时，反而得到了-1,3-二磷杂(III)-2,4-二氮杂环戊烷-AuCl配合物。我们在此展示的结果为通过一锅法选择性地制备此类配位化合物提供了一种新策略。
