Seasonal shift of water quality in China Yangtze River and its impacts on membrane fouling development during the drinking water supply by membrane distillation system.

Membrane distillation (MD) technique is increasingly regarded as a promising process for drinking water supply and wastewater treatment owing to its great water purification and usage of renewable energy. Like other membrane separation processes, the membrane fouling issue is widely considered as the main obstacle for real applications of large-scale MD systems. Feedwater characteristics, as the predominant factors for membrane fouling layer formation, mostly determined the membrane fouling trend of MD. Thus the impacts of seasonal shifts of initial feedwater quality on the MD membrane fouling were detailedly researched in this study, and the biofilm development mechanism was especially explored. The bacterial community structure of membrane biofilms was clearly clarified in MD runs of Yangtze River waters that collected in four seasons. The results revealed that the winter run posed a quite sharp flux drop, while a relatively milder flux decline behaviour was seen for other groups despite of the higher bacteria concentration of initial feedwaters. The poorer water quality in winter induced the establishment of a rather thick biofilm on the MD membrane, in which the biofilm-forming bacteria (Gammaproteobacteria and Alphaproteobacteria) and organic matters (EPS) were remarkably observed. Comparatively, a relatively thin biofilm containing abundant live cells and fewer organics finally formed in summer and autumn runs, causing a mitigated flux decline trend. Hence, it can be inferred that the membrane flux decline of MD was likely to be more sensitive to the organic attachment on the membrane in comparison with the bacteria adhesion. Finally, a three-phase pretreatment method was suggested for MD fouling control, including heating course, sterilization course, and filtration course.