Refinery and Petrochemicals Technology Research Center (RPTC), Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, Ho Chi Minh City, Viet Nam; Vietnam National University Ho Chi Minh City (VNU-HCM), Linh Trung ward, Thu Duc District, Ho Chi Minh City, Viet Nam.
Van Hien University, Ho Chi Minh City, Viet Nam.
Chemosphere. 2022 Feb;289:133249. doi: 10.1016/j.chemosphere.2021.133249. Epub 2021 Dec 11.
Improvement of biomass utilization productivity following cascading strategy is a priority for the biorefinery-based circular bioeconomy. In recent years, the field of energy research has seen an increasing interest in bio-products from paddy-based biorefinery, but the utilization of the entire value of paddy biomass to guide the commercial viability of its products has not been got feasible outcomes. Here we propose a potential pathway for a conceptual paddy biorefinery framework by addressing wastes for producing more products. The feasibility of the integrated biorefinery was demonstrated by the conversion of wastes into value-added products such as nano-silica and lignin. In particular, this is the first time that silica recovered from bioethanol system was continued to be reused to produce ZSM-5 and Ni/ZSM-5 as catalysts of rice straw lignin depolymerization achieving high conversion of lignin up to 95% and fair yield of phenolic products up to 41%. Material flow of an integrated biorefinery model was reported to give a future outlook for making most of the processing routes of rice residues. We also established a life cycle that follows the circular bioeconomy concept and discussed the relationship between each of potential bioproducts and their market opportunities.
基于级联策略提高生物质利用生产力是基于生物炼制的循环生物经济的首要任务。近年来,能源研究领域对稻基生物炼制的生物产品越来越感兴趣,但尚未从整体上利用稻生物质的价值来指导其产品的商业可行性。在这里,我们通过解决废物利用问题,提出了一种概念性的稻生物炼制框架的潜在途径,以生产更多的产品。通过将废物转化为附加值产品,如纳米二氧化硅和木质素,验证了综合生物炼制的可行性。特别是,这是首次将从生物乙醇系统中回收的硅继续用于生产 ZSM-5 和 Ni/ZSM-5,作为水稻秸秆木质素解聚的催化剂,实现木质素高达 95%的高转化率和酚类产物高达 41%的良好产率。还报告了综合生物炼制模型的物料流,为最大限度地利用稻渣的加工路线提供了未来的前景。我们还建立了一个遵循循环生物经济概念的生命周期,并讨论了每个潜在生物制品及其市场机会之间的关系。