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膜蒸馏:预处理对污垢动力学的影响

Membrane Distillation: Pre-Treatment Effects on Fouling Dynamics.

作者信息

Santos Paula G, Scherer Cíntia M, Fisch Adriano G, Rodrigues Marco Antônio S

机构信息

Graduation Program in Environmental Quality, Universidade Feevale, Novo Hamburgo 93525-075, Brazil.

Chemical Engineering Department, Universidade Feevale, Novo Hamburgo 93525-075, Brazil.

出版信息

Membranes (Basel). 2021 Dec 3;11(12):958. doi: 10.3390/membranes11120958.

DOI:10.3390/membranes11120958
PMID:34940459
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8706986/
Abstract

In the research reported in this paper, membrane distillation was employed to recover water from a concentrated saline petrochemical effluent. According to the results, the use of membrane distillation is technically feasible when pre-treatments are employed to mitigate fouling. A mathematical model was used to evaluate the fouling mechanism, showing that the deposition of particulate and precipitated material occurred in all tests; however, the fouling dynamic depends on the pre-treatment employed (filtration, or filtration associated with a pH adjustment). The deposit layer formed by particles is not cohesive, allowing its entrainment to the bulk flow. The precipitate fouling showed a minimal tendency to entrainment. Also, precipitate fouling served as a coupling agent among adjacent particles, increasing the fouling layer cohesion.

摘要

在本文报道的研究中,采用膜蒸馏从浓缩的石化含盐废水中回收水。结果表明,当采用预处理来减轻结垢时,膜蒸馏的应用在技术上是可行的。使用数学模型评估结垢机制,结果表明在所有测试中均发生了颗粒和沉淀物质的沉积;然而,结垢动态取决于所采用的预处理(过滤,或与pH调节相关的过滤)。由颗粒形成的沉积层没有粘性,使得其能够被夹带至主流体中。沉淀结垢显示出最小的被夹带趋势。此外,沉淀结垢充当相邻颗粒之间的耦合剂,增加了结垢层的凝聚力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/40e682267dfd/membranes-11-00958-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/49d4023c8498/membranes-11-00958-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/2b8588eb64ad/membranes-11-00958-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/37f59ce00ab4/membranes-11-00958-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/9190b3c07240/membranes-11-00958-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/2b80b219097e/membranes-11-00958-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/6ccda039aa91/membranes-11-00958-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/12709775390c/membranes-11-00958-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/448dd05c6252/membranes-11-00958-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/74a5346da613/membranes-11-00958-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/6fc5425cb8e1/membranes-11-00958-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/5b2e95b0c39e/membranes-11-00958-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/adb618080693/membranes-11-00958-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/ccc340248f9c/membranes-11-00958-g013a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/40e682267dfd/membranes-11-00958-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/49d4023c8498/membranes-11-00958-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/2b8588eb64ad/membranes-11-00958-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/37f59ce00ab4/membranes-11-00958-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/9190b3c07240/membranes-11-00958-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/2b80b219097e/membranes-11-00958-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/6ccda039aa91/membranes-11-00958-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/12709775390c/membranes-11-00958-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/448dd05c6252/membranes-11-00958-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/74a5346da613/membranes-11-00958-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/6fc5425cb8e1/membranes-11-00958-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/5b2e95b0c39e/membranes-11-00958-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/adb618080693/membranes-11-00958-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/ccc340248f9c/membranes-11-00958-g013a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ecc/8706986/40e682267dfd/membranes-11-00958-g014.jpg

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本文引用的文献

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Desalination of Produced Water by Membrane Distillation: Effect of the Feed Components and of a Pre-treatment by Fenton Oxidation.膜蒸馏淡化采出水:进料成分的影响和芬顿氧化预处理的影响。
Sci Rep. 2019 Oct 18;9(1):14964. doi: 10.1038/s41598-019-51167-z.
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Recent advances in membrane development for treating surfactant- and oil-containing feed streams via membrane distillation.膜蒸馏处理含表面活性剂和油的进料流的膜开发的最新进展。
Adv Colloid Interface Sci. 2019 Nov;273:102022. doi: 10.1016/j.cis.2019.102022. Epub 2019 Aug 28.
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Fouling and wetting in the membrane distillation driven wastewater reclamation process - A review.
膜蒸馏驱动的废水回收过程中的污垢和润湿——综述
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Antiwetting and Antifouling Janus Membrane for Desalination of Saline Oily Wastewater by Membrane Distillation.用于膜蒸馏法处理含盐含油废水的超疏水防污Janus膜
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Comparison of colloidal silica involved fouling behavior in three membrane distillation configurations using PTFE membrane.比较三种不同膜蒸馏构型中使用 PTFE 膜时胶体二氧化硅的污染行为。
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