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MoS 纳米阵列和 MoO 纳米带的构建:用于去除 Pb(II)、Au(III) 和亚甲基蓝的两种高效吸附剂。

Construction of MoS nanoarrays and MoO nanobelts: Two efficient adsorbents for removal of Pb(II), Au(III) and Methylene Blue.

机构信息

College of Chemistry and Pharmacy, Northwest A&F University, Yangling, Shaanxi 712100, China.

State Key Laboratory of Photoelectric Technology and Functional Materials, International Collaborative Center on Photoelectric Technology and Nano Functional Materials, Institute of Photonics & Photon-Technology, Northwest University, Xi'an 710069, China.

出版信息

J Environ Sci (China). 2022 Jan;111:38-50. doi: 10.1016/j.jes.2021.02.031. Epub 2021 Mar 19.

Abstract

Toxic heavy metal ions, valuable noble metal ions and organic dyes are significant concerns in wastewater treatment. In this work, MoO nanobelts (MoO NBs) prepared by solvothermal method and MoS nanoarrays (MoS NAs) constructed using MoO NBs precursor were proposed to effectively remove heavy/noble metal ions and organic dyes, such as Pb, Au and Methylene Blue (MB). The two adsorbents exhibited the excellent adsorption capacity towards Pb, Au and MB. The maximum removal capacity of Pb and MB on MoO NBs was 684.93 mg/g and 1408 mg/g, respectively, whereas that of Au and MB on MoS NAs was 1280.2 mg/g and 768 mg/g, respectively. Furthermore, the thermodynamic parameters were calculated from the temperature-dependent curves, suggesting that the removal of Pb and Au on both adsorbents was spontaneous and endothermic. The new adsorbents introduced here were high adsorption activity, ease of fabrication, high scalability, good chemical stability, great repeatability and abundant and cheap supply, which were highly attractive for wastewater treatment.

摘要

有毒重金属离子、有价值的贵金属离子和有机染料是废水处理中需要关注的重要问题。在这项工作中,采用溶剂热法制备的 MoO 纳米带(MoO NBs)和使用 MoO NBs 前体制备的 MoS 纳米阵列(MoS NAs)被提出用于有效去除重金属/贵金属离子和有机染料,如 Pb、Au 和亚甲蓝(MB)。这两种吸附剂对 Pb、Au 和 MB 表现出优异的吸附能力。MoO NBs 对 Pb 和 MB 的最大去除容量分别为 684.93mg/g 和 1408mg/g,而 MoS NAs 对 Au 和 MB 的最大去除容量分别为 1280.2mg/g 和 768mg/g。此外,通过温度相关曲线计算了热力学参数,表明两种吸附剂上 Pb 和 Au 的去除均是自发和吸热的。这里引入的新型吸附剂具有高吸附活性、易于制造、高可扩展性、良好的化学稳定性、良好的可重复性以及丰富且廉价的供应,这对废水处理极具吸引力。

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