Adenosine-functionalized UiO-66-NH to efficiently remove Pb(II) and Cr(VI) from aqueous solution: Thermodynamics, kinetics and isothermal adsorption.

A new zirconium-based adsorption material (UiO-66-AMP) was prepared by modifying UiO-66-NH with 5-adenosine to effectively remove Pb(II) and Cr(VI) from wastewater. The SEM, EDS, XRS and FT-IR characterization confirmed the successful synthesis of UiO-66-AMP. We conducted a sets of experiments to test the adsorption effectiveness of UiO-66-AMP for Pb(II) and Cr(VI). The maximum adsorption capacity of UiO-66-AMP for Cr(VI) (pH=2) and Pb(II) (pH=4) are 196.60 and 189.69 mg/g, respectively. The adsorption process conforms to the pseudo-second-order and Langmuir models, which indicates that the adsorption is a single-layer chemical process. Gibbs free energy (∆G) indicates that the adsorption of Pb(II) is an exothermic reaction, while the adsorption of Cr(VI) is an endothermic reaction. At the same time, the adsorbent maintains excellent adsorption capacity at least after 4 cycles. The good adsorption performance of UiO-66-AMP towards the metal ions was attributed to the surface complexation and electrostatic interactions. Therefore, the new adsorbent has obvious application prospect to remove Pb(II) and Cr(VI) from wastewater.