Development of LnMnO perovskite on low temperature Hg removal.

LnMnO (Ln = La, Pr, Nd, Sm, Eu, Gd or Dy) perovskites synthesized by sol-gel method were employed for gaseous elemental mercury (Hg) removal from coal-fired flue gas. Characterization results revealed the structure of the perovskites presented a phase transition process from rhombohedral system to O- and O'-orthorhombic structure with the change of A-site rare earth elements. The perovskites showed satisfactory Hg removal capacity in a narrow temperature range of 100-150°C. NdMnO with an O-O' orthorhombic structure presented the best Hg removal performance, which markedly depends on four factors: crystal structure, oxygen vacancy density, Mn/Mn ratio and surface element segregation. The Hg removal mechanism was illustrated based on the mercury temperature programmed desorption experiment and X-ray photoelectron spectroscopy characterization. Both chemisorption and catalytic oxidation played a role in the Hg removal process. Chemisorption dominated the Hg removal, due to the slow catalytic oxidation rate at low temperature. This work preliminarily established the relation between the structure of rare earth manganese perovskite and Hg removal performance.