Beijing Key Laboratory of Quality Evaluation Technology for Hygiene, and Safety of Plastics, College of Chemistry and Materials Engineering, Beijing Technology and Business University, 100048, Beijing, People's Republic of China.
Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, 214122, Jiangsu, People's Republic of China.
Chemphyschem. 2022 Feb 16;23(4):e202100778. doi: 10.1002/cphc.202100778. Epub 2022 Jan 18.
In order to reduce the pollutants of environment and electromagnetic waves, environment friendly polymer foams with outstanding electromagnetic interference shielding are imminently required. In this paper, a kind of electromagnetic shielding, biodegradable nanocomposite foam was fabricated by blending poly (butylene succinate) (PBS) with carbon nanotubes (CNTs) followed by foaming with supercritical CO . The crystallization temperature and melting temperature of PBS/CNTs nanocomposites with 4 wt % of CNTs increased remarkably by 6 °C and 3.1 °C compared with that of pure PBS and a double crystal melting peak of various PBS samples appeared in DSC curves. Increasing the CNT content from 0 to 4 wt % leads to an increase of approximately 3 orders of magnitude in storage modulus and nearly 9 orders of magnitude in enhancement of electrical properties. Furthermore, CNTs endowed PBS nanocomposite foam with adjustable electromagnetic interference (EMI) shielding property, giving a specific EMI shielding effectiveness of 28.5 dB cm /g. This study provides a promising methodology for preparing biodegradable, lightweight PBS/CNTs foam with outstanding electromagnetic shielding properties.
为了减少环境污染物和电磁波,迫切需要具有优异电磁干扰屏蔽性能的环保型聚合物泡沫。本文通过将聚丁二酸丁二醇酯(PBS)与碳纳米管(CNTs)共混,然后用超临界 CO 发泡,制备了一种电磁屏蔽、可生物降解的纳米复合材料泡沫。与纯 PBS 相比,添加 4wt% CNTs 的 PBS/CNTs 纳米复合材料的结晶温度和熔融温度分别显著提高了 6°C 和 3.1°C,并且各种 PBS 样品的 DSC 曲线中出现了双结晶熔融峰。随着 CNT 含量从 0 增加到 4wt%,储能模量增加了约 3 个数量级,电性能增强了近 9 个数量级。此外,CNTs 赋予 PBS 纳米复合材料泡沫可调节的电磁干扰(EMI)屏蔽性能,使其具有特定 EMI 屏蔽效能 28.5dB·cm/g。本研究为制备具有优异电磁屏蔽性能的可生物降解、质轻的 PBS/CNTs 泡沫提供了一种有前途的方法。