Z-scheme WO/PANI heterojunctions with enhanced photocatalytic activity under visible light: A depth experimental and DFT studies.

A WO@PANI heterojunction photocatalyst with a various mass ratio of polyaniline to WO was obtained via the in situ oxidative deposition polymerization of aniline monomer in the presence of WO powder. The characterization of WO@PANI composites was carried via X-ray diffraction (XRD), scanning electron microscopy (SEM-EDS), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible diffuse reflection spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and photoluminescence spectroscopy (PL). The photocatalytic efficiency of WO@PANI photocatalysts was assessed by following the decomposition of the Rhodamine B (RhB) dye under visible light irradiation (λ >420 nm). The results evidenced the high efficiency of the WO@PANI (0.5 wt %) nanocomposite in the photocatalytic degradation of RhB (90% within 120 min) under visible light irradiation 3.6 times compared to pure WO. The synergistic effect between PANI and WO is the reason for the increased photogenerated carrier separation. The superior photocatalytic performance of the WO@PANI catalyst was ascribed to the increased visible light in the visible range and the efficient charge carrier separation. Furthermore, the Density Functional Theory study (DFT) of WO@PANI was performed at the molecular level, to find its internal nature for the tuning of photocatalytic efficiency. The DFT results indicated that the chemical bonds connected the solid-solid contact interfaces between WO and PANI. Finally, a plausible photocatalytic mechanism of WO@PANI (0.5 wt %) performance under visible light illumination is suggested to guide additional photocatalytic activity development.