School of Mechanical Engineering, University of Jinan, Jinan, 250022, China.
Measurement and Testing Center of Shandong Province, Jinan, 250014, China.
J Mater Sci Mater Med. 2022 Jan 4;33(1):9. doi: 10.1007/s10856-021-06637-0.
In recent years, along with the development and application of magnesium alloys, magnesium alloys have been widely used in automotive, aerospace, medicine, sports, and other fields. In the field of medical materials, magnesium not only has the advantage of light weight, high strength, and a density similar to that of human bone, but also has good biocompatibility and promotes the growth of human bone. However, the mechanical properties and corrosion resistance of magnesium alloys need to be further improved to meet the requirements for human biodegradable implants. In this study, three alloys (mass fractions: Mg-10Zn, Mg-20Zn, and Mg-30Zn (wt.%)) were prepared using powder metallurgy by homogeneously mixing powders of the above materials in a certain amount with magnesium as the substrate through the addition of zinc elements, which also have good biocompatibility. The effect of zinc on the microstructure, mechanical properties, wear performance, and corrosion resistance of magnesium-zinc alloys was studied when the zinc content was different. The results show that compared with the traditional magnesium alloy using powder metallurgy, prepared magnesium alloy has good resistance to compression and bending, its maximum compressive stress can reach up to 318.96 MPa, the maximum bending strength reached 189.41 MPa, and can meet the mechanical properties of the alloy as a human bone-plate requirements. On the polarization curve, the maximum positive shift of corrosion potential of the specimens was 73 mv and the maximum decrease of corrosion-current density was 53.2%. From the comparison of the above properties, it was concluded that the three prepared alloys of which Mg-20% Zn had the best overall performance. Its maximum compressive stress, maximum bending strength, and corrosion-current density reached 318.96 MPa, 189.41 MPa and 2.08 × 10 A·cm respectively, which are more suitable for use as human implant bone splints in human-body fluid environment. The mechanical properties of the sintered Mg-Zn alloys were analyzed using powder-metallurgy techniques, and their microstructure, micromotion wear properties, electrochemical corrosion properties and composition of the physical phases were analyzed and discussed.
近年来,随着镁合金的发展和应用,镁合金已广泛应用于汽车、航空航天、医学、体育等领域。在医用材料领域,镁不仅具有重量轻、强度高、密度与人骨相近的优点,而且具有良好的生物相容性,促进了人骨的生长。然而,镁合金的力学性能和耐腐蚀性需要进一步提高,以满足人体可生物降解植入物的要求。在这项研究中,使用粉末冶金技术通过在一定量的上述材料粉末中添加锌元素,均匀混合作为基底的镁,制备了三种合金(质量分数:Mg-10Zn、Mg-20Zn 和 Mg-30Zn(wt.%)),这些合金也具有良好的生物相容性。研究了锌含量不同时锌对镁-锌合金微观结构、力学性能、磨损性能和耐腐蚀性的影响。结果表明,与传统的粉末冶金镁合金相比,所制备的镁合金具有良好的抗压和抗弯性能,其最大压缩应力可达 318.96 MPa,最大弯曲强度可达 189.41 MPa,可满足作为人体骨板的合金力学性能要求。在极化曲线上,试样腐蚀电位的最大正移为 73 mV,腐蚀电流密度的最大减小为 53.2%。从上述性能的比较来看,认为三种所制备的合金中 Mg-20%Zn 的综合性能最好。其最大压缩应力、最大弯曲强度和腐蚀电流密度分别达到 318.96 MPa、189.41 MPa 和 2.08×10 A·cm,更适合在人体体液环境中用作人体植入骨夹板。采用粉末冶金技术对烧结 Mg-Zn 合金的力学性能进行了分析,并对其微观结构、微动磨损性能、电化学腐蚀性能和物理相组成进行了分析和讨论。