Chemical composition of microplastics floating on the surface of the Mediterranean Sea.

The Mediterranean Sea is one of the most studied regions in the world in terms of microplastic (MP) contamination. However, only a few studies have analysed the chemical composition of MPs at the Mediterranean Sea surface. In this context, this study aims to describe the chemical composition as a function of particle size, mass and number concentrations of MPs collected in the surface waters of the Mediterranean Sea. The chemical composition showed a certain homogeneity at the Mediterranean Sea scale. The main polymers identified by Fourier Transform Infra-Red (FTIR) spectroscopy were poly(ethylene) (67.3 ± 2.4%), poly(propylene) (20.8 ± 2.1%) and poly(styrene) (3.0 ± 0.9%). Nevertheless, discrepancies, confirmed by the literature, were observed at a mesoscale level. Thus, in the North Tyrrhenian Sea, the proportion of poly(ethylene) was significantly lower than the average value of the Mediterranean Sea (57.9 ± 10.5%). Anthropic sources, rivers, or polymer ageing are assumed to be responsible for the variations observed.