Nokhrin Aleksey, Shadrina Iana, Chuvil'deev Vladimir, Kopylov Vladimir, Berendeev Nikolay, Murashov Artem, Bobrov Aleksandr, Tabachkova Nataliya, Smirnova Elena, Faddeev Mikhail
Materials Science Department, Physical-Technical Research Institute, Lobachevsky State University of Nizhniy Novgorod, 603022 Nizhny Novgorod, Russia.
Laboratory of Vacuum Plasma Coating, Physical-Technical Institute, National Academy of Sciences of Belarus, 220141 Minsk, Belarus.
Materials (Basel). 2021 Dec 27;15(1):185. doi: 10.3390/ma15010185.
Thermal stability of composite bimetallic wires from five novel microalloyed aluminum alloys with different contents of alloying elements (Zr, Sc, and Hf) is investigated. The alloy workpieces were obtained by induction-casting in a vacuum, preliminary severe plastic deformation, and annealing providing the formation of a uniform microstructure and the nucleation of stabilizing intermetallide Al(Zr,Sc,Hf) nanoparticles. The wires of 0.26 mm in diameter were obtained by simultaneous deformation of the Al alloy with Cu shell. The bimetallic wires demonstrated high strength and improved thermal stability. After annealing at 450-500 °C, a uniform fine-grained microstructure formed in the wire (the mean grain sizes in the annealed Al wires are 3-5 μm). An increased hardness and strength due to nucleation of the Al(Sc,Hf) particles was observed. A diffusion of Cu from the shell into the surface layers of the Al wire was observed when heating up to 400-450 °C. The Cu diffusion depth into the annealed Al wire surfaces reached 30-40 μm. The maximum elongation to failure of the wires (20-30%) was achieved after annealing at 350 °C. The maximum values of microhardness (H = 500-520 MPa) and of ultimate strength (σ = 195-235 MPa) after annealing at 500 °C were observed for the wires made from the Al alloys alloyed with 0.05-0.1% Sc.
研究了五种含有不同合金元素(Zr、Sc和Hf)含量的新型微合金化铝合金复合双金属丝的热稳定性。合金工件通过真空感应铸造、初步的严重塑性变形和退火获得,从而形成均匀的微观结构并使稳定的金属间化合物Al(Zr,Sc,Hf)纳米颗粒形核。直径为0.26 mm的金属丝通过铝合金与铜壳同时变形获得。双金属丝表现出高强度和改善的热稳定性。在450 - 500 °C退火后,金属丝中形成了均匀的细晶微观结构(退火后的铝丝平均晶粒尺寸为3 - 5 μm)。观察到由于Al(Sc,Hf)颗粒的形核导致硬度和强度增加。在加热到400 - 450 °C时,观察到铜从壳层扩散到铝丝的表层。铜扩散到退火后的铝丝表面的深度达到30 - 40 μm。在350 °C退火后,金属丝的最大断裂伸长率达到20 - 30%。对于含有0.05 - 0.1% Sc的铝合金制成的金属丝,在500 °C退火后观察到显微硬度(H = 500 - 520 MPa)和极限强度(σ = 195 - 235 MPa)的最大值。