Yan Xiaoxing, Li Wenbo, Han Yan, Yin Taiyu
Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China.
College of Furnishings and Industrial Design, Nanjing Forestry University, Nanjing 210037, China.
Polymers (Basel). 2021 Dec 25;14(1):72. doi: 10.3390/polym14010072.
The melamine/rice husk powder-coated shellac microcapsules were prepared by in-situ polymerization with melamine resin mixed with rice husk powder as microcapsule wall material and shellac as microcapsule core material. The effect of the addition amount of microcapsules with different wall material ratios on the performance of wood waterborne primer coating was investigated. The results show that the most important factor affecting the performance of microcapsules is the content of rice husk powder. Through the preparation and analysis of shellac microcapsule primer coating coated with melamine/rice husk powder, when the content of microcapsule powder is 0-6%, it has little effect on the optical properties of wood waterborne primer coating, and the microcapsule with 5.5% rice husk powder has little effect on the color difference of primer coating. The coating hardness increases with the increase of rice husk powder content in wall material. When the rice husk powder content in wall material is more than 5.5%, the coating hardness reaches the best. When the content of microcapsule powder is 3.0-9.0%, the adhesion of the coating is better, and the coating with rice husk powder content of 5.5% in microcapsule wall material has better impact resistance. When the content of rice husk powder was 5.5% and the content of microcapsule powder was 6%, the elongation at break of the primer coating was the highest and the tensile resistance was the best. The composition of wood waterborne primer did not change after adding microcapsule. The water-based primer with microcapsule has better aging resistance. The water-based primer coating with rice husk powder content of 5.5% and the addition amount of 6% had the best comprehensive performance, which lays the technical reference for the toughness and self-repairing of the waterborne wood coatings.
以三聚氰胺树脂与稻壳粉混合作为微胶囊壁材、紫胶作为微胶囊芯材,通过原位聚合法制备了三聚氰胺/稻壳粉包覆紫胶微胶囊。研究了不同壁材比例微胶囊添加量对水性木器底漆性能的影响。结果表明,影响微胶囊性能的最重要因素是稻壳粉含量。通过对三聚氰胺/稻壳粉包覆紫胶微胶囊底漆涂层的制备与分析,当微胶囊粉含量为0-6%时,对水性木器底漆的光学性能影响较小,稻壳粉含量为5.5%的微胶囊对底漆涂层色差影响较小。涂层硬度随壁材中稻壳粉含量的增加而增大,当壁材中稻壳粉含量超过5.5%时,涂层硬度达到最佳。当微胶囊粉含量为3.0-9.0%时,涂层附着力较好,微胶囊壁材中稻壳粉含量为5.5%的涂层具有较好的耐冲击性。当稻壳粉含量为5.5%、微胶囊粉含量为6%时,底漆涂层的断裂伸长率最高,抗拉性能最佳。添加微胶囊后水性木器底漆的组成未发生变化。含微胶囊的水性底漆具有较好的耐老化性能。稻壳粉含量为5.5%、添加量为6%的水性底漆涂层综合性能最佳,为水性木器涂料的韧性和自修复性奠定了技术参考。