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用于改善聚丙烯机械性能的添加剂的统计研究

Statistical Study on Additives Used to Improve Mechanical Properties of Polypropylene.

作者信息

Yousef N S

机构信息

Petrochemical Department, Faculty of Engineering, Pharos University, Canal El Mahmoudeya St. Semouha, Alexandria 21311, Egypt.

出版信息

Polymers (Basel). 2022 Jan 3;14(1):179. doi: 10.3390/polym14010179.

Abstract

Polypropylene (PP) is a semi-crystalline polymer that is brittle under severe conditions. To meet industry needs, and to increase the applications of polypropylene, its mechanical properties should be improved. In this research, the mechanical properties of polypropylene, such as tensile strength at break, tensile strength at yield, % elongation, and Young's modulus, were improved using two types of additives. Additives used were calcium carbonate master batch filler composed of 80% calcium carbonate and 20% polyethylene, and a mixture of linear low-density polyethylene (LLDPE)/low density polyethylene (LDPE). Results showed that both tensile strength at break, and tensile strength at yield, decrease with increasing the amount of both additives. Percentage elongation of PP increased using both additives. The modulus of elasticity of PP increases by increasing the amount of both additives, until a value of 20 wt%. Analysis of variance (ANOVA test) or (F-test) shows significant differences between the effect of different weights of LLDPE/LDPE mixture and calcium carbonate filler on the four mechanical properties of polypropylene studied at a level of 0.05. T-tests are applied to compare between the effect of both calcium carbonate master batch filler and the mixture LLDPE/LDPE on the four mechanical properties of polypropylene studied. T-tests show no significant differences between the effect of both calcium carbonate master batch filler and the mixture LLDPE/LDPE on all mechanical properties of polypropylene studied at a level of 0.05.

摘要

聚丙烯(PP)是一种半结晶聚合物,在严苛条件下易碎。为满足行业需求并增加聚丙烯的应用,其机械性能需得到改善。在本研究中,使用两种添加剂来改善聚丙烯的机械性能,如断裂拉伸强度、屈服拉伸强度、伸长率和杨氏模量。所使用的添加剂为碳酸钙母粒填料(由80%碳酸钙和20%聚乙烯组成)以及线性低密度聚乙烯(LLDPE)/低密度聚乙烯(LDPE)的混合物。结果表明,随着两种添加剂用量的增加,断裂拉伸强度和屈服拉伸强度均降低。使用这两种添加剂时,PP的伸长率均增加。PP的弹性模量随着两种添加剂用量的增加而增大,直至达到20 wt%的值。方差分析(ANOVA检验或F检验)表明,在0.05的显著性水平下,不同重量的LLDPE/LDPE混合物和碳酸钙填料对所研究的聚丙烯的四种机械性能的影响存在显著差异。应用T检验来比较碳酸钙母粒填料和LLDPE/LDPE混合物对所研究的聚丙烯的四种机械性能的影响。T检验表明,在0.05的显著性水平下,碳酸钙母粒填料和LLDPE/LDPE混合物对所研究的聚丙烯的所有机械性能的影响之间没有显著差异。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6984/8747261/a21fda5e26df/polymers-14-00179-g001.jpg

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