Flexible Triboelectric Nanogenerators Based on Electrospun Poly(vinylidene fluoride) with MoS/Carbon Nanotube Composite Nanofibers.

With the miniaturization of wearable smart devices, the demand for portable and sustainable power sources is increasing. Herein, a flexible and lightweight triboelectric nanogenerator (PMC-TENG) was fabricated with MoS/carbon nanotube (MC)-doped PVDF as the friction substrate based on electrospinning for harvesting random body motion energy under complex mechanical deformations. The charge density on the friction surface of PVDF nanofibers was found to increase significantly as the introduced electron acceptor of the MC composite, and nylon as a clothing material for another friction layer simplifies the structure of the device. Upon optimization of the electrospinning preparation process, the output voltage of the prepared PMC-TENG can reach >300 V and the instantaneous power can reach 0.484 mW (∼6 cm × 6 cm). At the same time, the PMC-TENG remains stable over 3000 cycles and has the ability to charge a capacitor. The flexible device demonstrates an excellent capability of converting mechanical energy to electrical energy. Therefore, this study has good prospects for application in the field of power supply for portable electronic devices and others.