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手性活性浴中的二聚体胶体包含物:有效相互作用和手性诱导扭矩。

Dimeric colloidal inclusion in a chiral active bath: Effective interactions and chirality-induced torque.

作者信息

Torrik Abdolhalim, Naji Ali, Zarif Mahdi

机构信息

Department of Physical and Computational Chemistry, Shahid Beheshti University, Tehran 19839-9411, Iran.

School of Nano Science, Institute for Research in Fundamental Sciences (IPM), Tehran 19395-5531, Iran.

出版信息

Phys Rev E. 2021 Dec;104(6-1):064610. doi: 10.1103/PhysRevE.104.064610.

Abstract

Colloidal inclusions suspended in a bath of smaller particles experience an effective bath-mediated attraction at small intersurface separations, which is known as the depletion interaction. In an active bath of nonchiral self-propelled particles, the effective force changes from attraction to repulsion, an effect that is suppressed when the active bath particles are chiral. Using Brownian dynamics simulations, we study the effects of channel confinement and bath chirality on the effective forces and torques that are mediated between two inclusions that may be fixed within the channel or may be allowed to rotate freely as a rigid dimer around its center of mass. We show that the confinement has a strong effect on the effective interactions, depending on the orientation of the dimer relative to the channel walls. The active particle chirality leads to a force imbalance and, hence, a net torque on the inclusion dimer, which we investigate as a function of the bath chirality strength and the channel height.

摘要

悬浮在较小颗粒浴中的胶体夹杂物在小的界面间距下会经历一种有效的由浴介导的吸引力,这被称为排空相互作用。在非手性自驱动颗粒的活性浴中,有效力从吸引力变为排斥力,当活性浴颗粒为手性时,这种效应会受到抑制。利用布朗动力学模拟,我们研究了通道限制和浴手性对两个夹杂物之间介导的有效力和扭矩的影响,这两个夹杂物可能固定在通道内,或者可能作为一个刚性二聚体围绕其质心自由旋转。我们表明,限制对有效相互作用有很强的影响,这取决于二聚体相对于通道壁的取向。活性颗粒的手性会导致力的不平衡,从而在夹杂物二聚体上产生净扭矩,我们将其作为浴手性强度和通道高度的函数进行研究。

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