School of Physics, Institute for Research in Fundamental Sciences (IPM), Tehran 19395-5531, Iran.
J Chem Phys. 2017 Nov 21;147(19):194901. doi: 10.1063/1.5001505.
We study effective two- and three-body interactions between non-active colloidal inclusions in an active bath of chiral or non-chiral particles, using Brownian dynamics simulations within a standard, two-dimensional model of disk-shaped inclusions and active particles. In a non-chiral active bath, we first corroborate previous findings on effective two-body repulsion mediated between the inclusions by elucidating the detailed non-monotonic features of the two-body force profiles, including a primary maximum and a secondary hump at larger separations that was not previously reported. We then show that these features arise directly from the formation, and sequential overlaps, of circular layers (or "rings") of active particles around the inclusions, as the latter are brought to small surface separations. These rings extend to radial distances of a few active-particle radii from the surface of inclusions, giving the hard-core inclusions relatively thick, soft, repulsive "shoulders," whose multiple overlaps then enable significant (non-pairwise) three-body forces in both non-chiral and chiral active baths. The resulting three-body forces can even exceed the two-body forces in magnitude and display distinct repulsive and attractive regimes at intermediate to large self-propulsion strengths. In a chiral active bath, we show that, while active particles still tend to accumulate at the immediate vicinity of the inclusions, they exhibit strong depletion from the intervening region between the inclusions and partial depletion from relatively thick, circular zones further away from the inclusions. In this case, the effective, predominantly repulsive interactions between the inclusions turn to active, chirality-induced, depletion-type attractions, acting over an extended range of separations.
我们使用布朗动力学模拟,在二维盘状颗粒和活性颗粒的标准模型中,研究了非活性胶体颗粒在活性的手性或非手性粒子浴中的有效两体和三体相互作用。在手性非活性浴中,我们首先通过阐明两体力分布的详细非单调特征,证实了先前关于颗粒间有效两体排斥的发现,包括在较大分离处的主要最大值和次要驼峰,这在以前的报道中尚未发现。然后我们表明,这些特征直接源于活性粒子围绕颗粒形成的圆形层(或“环”)的形成和顺序重叠,因为后者被带到小的表面分离处。这些环延伸到颗粒表面几个人工粒子半径的径向距离,从而使硬芯颗粒具有相对较厚的、柔软的、排斥性的“肩部”,这些肩部的多次重叠然后在非手性和手性活性浴中产生显著的(非成对)三体力。由此产生的三体力甚至可以超过两体力的大小,并在手性活性浴中显示出明显的排斥和吸引区域。在手性活性浴中,我们表明,虽然活性粒子仍倾向于聚集在颗粒的附近区域,但它们在颗粒之间的间隔区域和远离颗粒的相对较厚的圆形区域表现出强烈的耗尽。在这种情况下,颗粒之间的有效、主要是排斥的相互作用变为活性的、手性诱导的、耗尽型吸引力,在较大的分离范围内起作用。