Sun Liying, Ge Shaocheng, Jing Deji, Liu Shuo, Chen Xi
College of Safety Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China.
Institute of Safely Science and Technology, Liaoning Technical University, Fuxin 123000, China.
ACS Omega. 2021 Dec 31;7(1):780-785. doi: 10.1021/acsomega.1c05422. eCollection 2022 Jan 11.
To solve the problem of poor dust wettability during coal mine dust treatment, sodium dodecyl sulfate (SDS) and alkyl glycoside (APG1214) were selected for compounding. An efficient, environmentally friendly, economical wetting agent was prepared. First, through molecular dynamics simulation studies, it was determined that the tail group C of SDS and APG1214 was adsorbed on the surface of bituminous coal, and the head groups S and O were adsorbed on the surface of water. The simulation result is found to be consistent with the surfactant solution dust removal theory, which proves the confidence of simulation. Then, by comparing the interaction of water-SDS and APG1214-bituminous coal and water-bituminous coal systems and the number of hydrogen bonds, the wetting mechanism of the SDS and APG1214 solution on bituminous coal was revealed. Finally, the surface tension, contact angle, and wetting time of different SDS and APG1214 solutions were determined by experiments and they decreased with decreasing mass fraction of SDS at the same concentration. The surface tension of the SDS and APG1214 solution and the number of micelles affected the wettability of bituminous coal. The optimal concentration of the SDS and APG1214 solution was 0.7%, and the optimal ratio was SDS/APG1214 = 1:3.
为解决煤矿粉尘治理过程中粉尘润湿性差的问题,选用十二烷基硫酸钠(SDS)和烷基糖苷(APG1214)进行复配,制备出一种高效、环保、经济的湿润剂。首先,通过分子动力学模拟研究确定,SDS和APG1214的尾基C吸附在烟煤表面,头基S和O吸附在水表面。发现模拟结果与表面活性剂溶液除尘理论一致,证明了模拟的可信度。然后,通过比较水-SDS和APG1214-烟煤体系与水-烟煤体系的相互作用及氢键数量,揭示了SDS和APG1214溶液对烟煤的润湿机理。最后,通过实验测定了不同SDS和APG1214溶液的表面张力、接触角和润湿时间,在相同浓度下,它们随SDS质量分数的降低而减小。SDS和APG1214溶液的表面张力和胶束数量影响烟煤的润湿性。SDS和APG1214溶液的最佳浓度为0.7%,最佳比例为SDS/APG1214 = 1:3。