Interface engineering of nickel Hydroxide-Molybdenum diselenide nanosheet heterostructure arrays for efficient alkaline hydrogen production.

The stacking of Molybdenum Diselenide (MoSe) nanomaterials as well as its poor intrinsic conductivity lead to sluggish water dissociation kinetics, which limit the performance of the alkaline hydrogen evolution reaction (HER). Herein, we constructed Nickel Hydroxide Ni(OH)-MoSe heterostructures directly on 3D self-supporting carbon cloth (CC) substrate via a simple hydrothermal and the subsequent chemical bath deposition process, then systemically studied the effect of the Ni(OH) deposition time on the HER performance. The synergistic effect between Ni(OH) and MoSe in the Ni(OH)-MoSe heterostructures optimizes the poor conductivity and Gibbs free energy for water adsorption, thus improving the water dissociation kinetics and giving rise to fast electron transfer in the HER process. The Ni(OH)-MoSe/CC constructed in this way with a Ni(OH) deposition times of 30 min performs good catalytic activities with a low overpotential of 130 mV at 10 mA cm, a low Tafel slope of 78.2 mV dec and good stability. Our results suggest that interface engineering combining with conductive substrate are conducive to enhance alkaline HER activity of MoSe and other similar transition metal dichalcogenides.