二维锆/铪异羟肟酸金属有机框架材料
Two-dimensional Zr/Hf-hydroxamate metal-organic frameworks.
作者信息
Lai Qiuxue, Chu Zhao-Qin, Xiao Xinyi, Dai Dejun, Song Ting, Luo Tian-Yi, Tang Wenlei, Feng Xuan, Zhang Zhiyuan, Li Tao, Xiao Hai, Su Jing, Liu Chong
机构信息
School of Chemical Engineering, Sichuan University, Chengdu, 610065, China.
College of Chemistry, Sichuan University, Chengdu, 610064, China.
出版信息
Chem Commun (Camb). 2022 Mar 15;58(22):3601-3604. doi: 10.1039/d2cc00213b.
Novel two-dimensional kagome metal-organic frameworks with mononuclear Zr/Hf nodes chelated by benzene-1,4-dihydroxamate linkers were synthesized. The MOFs, namely SUM-1, are chemically robust and kinetically favorable, as confirmed by theoretical and experimental studies. SUM-1(Zr) can be readily made into large (∼100 μm) single crystals and nanoplates (∼50 nm), constituting a versatile MOF platform.
合成了具有由苯-1,4-二异羟肟酸连接体螯合的单核锆/铪节点的新型二维戈薇金属有机框架。经理论和实验研究证实，这些金属有机框架（即SUM-1）具有化学稳定性和动力学优势。SUM-1(Zr)能够很容易地制成大尺寸（约100μm）的单晶和纳米片（约50nm），构成了一个多功能的金属有机框架平台。
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