Yu Sujuan, Wu Hongping, Yu Hongwei, Hu Zhanggui, Wang Jiyang, Wu Yicheng
Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, Tianjin University of Technology, Tianjin 300384, China.
Chem Commun (Camb). 2022 Feb 24;58(17):2834-2837. doi: 10.1039/d2cc00084a.
Borophosphates are an ideal material class for the design of deep-UV optical functional crystals, yet their practical applications are limited by their small birefringence. Herein, a new mixed-coordinated borophosphate, NH(BPO(OH))·HO, has been successfully designed and synthesized, which exhibits the largest birefringence of all reported borophosphates.
硼磷酸盐是用于设计深紫外光学功能晶体的理想材料类别,然而它们的实际应用受到其小双折射的限制。在此,一种新型的混合配位硼磷酸盐NH₄(BPO₃(OH))·H₂O已成功设计并合成,它展现出所有已报道硼磷酸盐中最大的双折射。