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通过热退火提高非晶态MoS薄膜的抗辐照性能

The Improvement of the Irradiation Resistance of Amorphous MoS Films by Thermal Annealing.

作者信息

Zhang Rui, Zhang Hong, Gao Xiaoming, Wang Peng

机构信息

State Key Laboratory of Solid lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China.

Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China.

出版信息

Nanomaterials (Basel). 2022 Jan 24;12(3):364. doi: 10.3390/nano12030364.

Abstract

Among the structural materials used in fusion reactors, amorphous materials can effectively inhibit the accumulation and growth of radiation-induced defects, thereby improving irradiation resistance. However, the application of solid lubricating materials should also consider the changes in their lubricating properties after irradiation. This study shows that the ability to inhibit the deterioration of lubricating properties is not reflected in the amorphous MoS film. When the ion fluence reached 4.34 × 10 ion/cm, its wear life was reduced by two orders of magnitude, reaching 8.2 × 10 revolutions. After the amorphous MoS film is vacuum annealed, its structural stability and resistance to deterioration of lubricating properties are improved. When the ion fluence reaches 1.09 × 10 ion/cm, for instance, the wear life of the MoS film annealed at 300 °C remains at 8.4 × 10 revolutions. The higher irradiation tolerance of MoS films comes from the reduction in intrinsic defects by thermal annealing, which increases the internal grain size and volume fraction of grain boundaries, further providing an effective sink for irradiation defects.

摘要

在聚变反应堆中使用的结构材料中,非晶态材料可以有效抑制辐射诱导缺陷的积累和生长,从而提高抗辐照性能。然而,固体润滑材料的应用还应考虑其辐照后润滑性能的变化。本研究表明,抑制润滑性能恶化的能力在非晶态MoS薄膜中并未体现。当离子注量达到4.34×10离子/cm时,其磨损寿命降低了两个数量级,降至8.2×10转。非晶态MoS薄膜经过真空退火后,其结构稳定性和抗润滑性能恶化能力得到提高。例如,当离子注量达到1.09×10离子/cm时,在300°C退火的MoS薄膜的磨损寿命仍保持在8.4×10转。MoS薄膜较高的辐照耐受性源于热退火使本征缺陷减少,这增加了内部晶粒尺寸和晶界体积分数,进一步为辐照缺陷提供了有效的阱。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7655/8838135/40059a37307b/nanomaterials-12-00364-g001.jpg

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