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用于熔融长丝制造的ASA-PEEK复合材料的合成与表征

Synthesis and Characterisation of ASA-PEEK Composites for Fused Filament Fabrication.

作者信息

Palacios-Ibáñez Belén, Relinque José J, Moreno-Sánchez Daniel, de León Alberto S, Delgado Francisco J, Escobar-Galindo Ramón, Molina Sergio I

机构信息

Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, IMEYMAT, Facultad de Ciencias, Campus Río San Pedro s/n, Universidad de Cádiz, 11510 Puerto Real (Cádiz), Spain.

Departamento de Física Aplicada, Escuela Politécnica Superior, Universidad de Sevilla, C/Virgen de África 7, 41011 Sevilla, Spain.

出版信息

Polymers (Basel). 2022 Jan 26;14(3):496. doi: 10.3390/polym14030496.

DOI:10.3390/polym14030496
PMID:35160484
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8838854/
Abstract

In this paper, a series of polymer composites made from acrylonitrile-styrene-acrylate (ASA) and poly (ether ether ketone) (PEEK) were manufactured. ASA acts as a polymer matrix while PEEK is loaded in the form of micro-particles that act as a reinforcing filler. The composites were compounded by single screw extrusion and then, different specimens were manufactured either via injection moulding (IM) or fused filament fabrication (FFF). Two different types of PEEK (commercial and reused) in different concentrations (3 and 6 wt.%) were tested and their influence in the mechanical, structural, and thermal properties were studied. It was observed that reused PEEK enhanced the stiffness and tensile strength and thermal stability of the composites both, for injected and printed specimens. This evidences the suitability of these composites as potential candidates as novel materials with enhanced properties following an approach of circular economy.

摘要

在本文中,制备了一系列由丙烯腈-苯乙烯-丙烯酸酯(ASA)和聚醚醚酮(PEEK)制成的聚合物复合材料。ASA作为聚合物基体,而PEEK以微粒形式负载,作为增强填料。复合材料通过单螺杆挤出进行混合,然后通过注塑成型(IM)或熔融长丝制造(FFF)制备不同的试样。测试了两种不同类型、不同浓度(3重量%和6重量%)的PEEK(商业级和回收级),并研究了它们对复合材料力学、结构和热性能的影响。结果表明,对于注塑和打印试样,回收级PEEK均提高了复合材料的刚度、拉伸强度和热稳定性。这证明了这些复合材料作为遵循循环经济方法的具有增强性能的新型材料的潜在候选材料的适用性。

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本文引用的文献

1
Applications of 3D-Printed PEEK via Fused Filament Fabrication: A Systematic Review.基于熔融长丝制造的3D打印聚醚醚酮的应用:一项系统综述。
Polymers (Basel). 2021 Nov 22;13(22):4046. doi: 10.3390/polym13224046.
2
Optimisation of Strength Properties of FDM Printed Parts-A Critical Review.熔融沉积成型(FDM)打印部件强度特性的优化——综述
Polymers (Basel). 2021 May 14;13(10):1587. doi: 10.3390/polym13101587.
3
Sustainable Additive Manufacturing: Mechanical Response of Polyamide 12 over Multiple Recycling Processes.可持续增材制造:聚酰胺12在多次回收过程中的力学响应。
Materials (Basel). 2021 Jan 19;14(2):466. doi: 10.3390/ma14020466.
4
Material Extrusion Additive Manufacturing of Wood and Lignocellulosic Filled Composites.木材和木质纤维素填充复合材料的材料挤出增材制造
Polymers (Basel). 2020 Sep 17;12(9):2115. doi: 10.3390/polym12092115.
5
Influence of Internal Innovative Architecture on the Mechanical Properties of 3D Polymer Printed Parts.内部创新结构对3D聚合物打印部件力学性能的影响。
Polymers (Basel). 2020 May 14;12(5):1129. doi: 10.3390/polym12051129.
6
Development of Surface-Coated Polylactic Acid/Polyhydroxyalkanoate (PLA/PHA) Nanocomposites.表面包覆聚乳酸/聚羟基脂肪酸酯(PLA/PHA)纳米复合材料的研制
Polymers (Basel). 2019 Mar 1;11(3):400. doi: 10.3390/polym11030400.
7
Low-Temperature Additive Manufacturing of Biomimic Three-Dimensional Hydroxyapatite/Collagen Scaffolds for Bone Regeneration.用于骨再生的仿生三维羟基磷灰石/胶原蛋白支架的低温增材制造
ACS Appl Mater Interfaces. 2016 Mar 23;8(11):6905-16. doi: 10.1021/acsami.6b00815. Epub 2016 Mar 9.
8
The influence of a compatibilizer on the thermal and dynamic mechanical properties of PEEK/carbon nanotube composites.增容剂对聚醚醚酮/碳纳米管复合材料热性能和动态力学性能的影响。
Nanotechnology. 2009 Aug 5;20(31):315707. doi: 10.1088/0957-4484/20/31/315707. Epub 2009 Jul 14.