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基于苝的发色团作为用于光放大的通用染料。

Perylene-Based Chromophore as a Versatile Dye for Light Amplification.

作者信息

Szukalska Alina, Szukalski Adam, Stachera Justyna, Zajac Dorota, Chrzumnicka Ewa, Martynski Tomasz, Mysliwiec Jaroslaw

机构信息

The Advanced Materials Engineering and Modelling Group, Faculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeze Stanislawa Wyspianskiego 27, 50-370 Wroclaw, Poland.

Faculty of Materials Engineering and Technical Physics, Poznan University of Technology, Piotrowo 3, 60-965 Poznan, Poland.

出版信息

Materials (Basel). 2022 Jan 27;15(3):980. doi: 10.3390/ma15030980.

Abstract

One of the challenges for modern optoelectronics is to find versatile, easily adaptable components for novel laser-based technologies. A very attractive perylene-derivative chromophore in different organic matrices for high-performance light amplification is discussed and outlined. Our approach demonstrates the outstandingly compatible laser dye and a viable strategy to provide an effective optical gain for stimulated emission enhancement. Through structural control, we produce simple optical devices embedded in organic matrices, such as poly(methyl methacrylate), nematic liquid crystalline (NLC) mixture, and a hybrid emulsion system (poly(vinyl alcohol) PVA + NLC mesophase). Importantly, we investigate and compare the spectroscopy of differently constructed organic systems in terms of stimulated-emission thresholds and light amplification process efficiency. Moreover, we report the effects of tunability for LC cells by an applied external electric field stimulus. Future directions of laser systems are outlined with an emphasis on the role of the perylene derivative. The studies meet current challenges in the field of modern organic technologies dedicated to various optoelectronic systems, including touch screens, displays, and Li-Fi networks.

摘要

现代光电子学面临的挑战之一是为基于激光的新技术找到通用、易于适配的组件。本文讨论并概述了一种在不同有机基质中用于高性能光放大的极具吸引力的苝衍生物发色团。我们的方法展示了出色的兼容激光染料以及为增强受激发射提供有效光学增益的可行策略。通过结构控制,我们制备了嵌入有机基质中的简单光学器件,如聚甲基丙烯酸甲酯、向列型液晶(NLC)混合物和混合乳液体系(聚乙烯醇PVA + NLC中间相)。重要的是,我们从受激发射阈值和光放大过程效率方面研究并比较了不同结构有机体系的光谱。此外,我们报告了施加外部电场刺激对液晶盒可调性的影响。概述了激光系统的未来发展方向,重点强调了苝衍生物的作用。这些研究满足了致力于各种光电子系统(包括触摸屏、显示器和光保真网络)的现代有机技术领域当前面临的挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/62d5/8838310/ed73a047fc76/materials-15-00980-g001.jpg

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