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利用石墨烯靶材在水中激光诱导产生氢气

Laser-Induced Generation of Hydrogen in Water by Using Graphene Target.

作者信息

Strek Wieslaw, Wiewiórski Przemysław, Miśta Włodzimierz, Tomala Robert, Stefanski Mariusz

机构信息

Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-422 Wroclaw, Poland.

出版信息

Molecules. 2022 Jan 22;27(3):718. doi: 10.3390/molecules27030718.

DOI:10.3390/molecules27030718
PMID:35163983
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8839270/
Abstract

A new method of hydrogen generation from water, by irradiation with CW infrared laser diode of graphene scaffold immersed in solution, is reported. Hydrogen production was extremely efficient upon admixing NaCl into water. The efficiency of hydrogen production increased exponentially with laser power. It was shown that hydrogen production was highly efficient when the intense white light emission induced by laser irradiation of graphene foam was occurring. The mechanism of laser-induced dissociation of water is discussed. It was found that hydrogen production was extremely high, at about 80%, and assisted by a small emission of O, CO and CO gases.

摘要

报道了一种通过用连续波红外激光二极管照射浸入溶液中的石墨烯支架从水中制氢的新方法。将氯化钠混入水中时,产氢效率极高。产氢效率随激光功率呈指数增长。结果表明,当石墨烯泡沫受激光照射产生强烈白光发射时,产氢效率很高。讨论了激光诱导水分解的机理。发现产氢率极高,约为80%,且有少量氧气、一氧化碳和二氧化碳气体排放辅助。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/12040df27cfd/molecules-27-00718-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/5d21e8d7198f/molecules-27-00718-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/6d4b76a084da/molecules-27-00718-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/7756242a6316/molecules-27-00718-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/28b1c75b9868/molecules-27-00718-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/12040df27cfd/molecules-27-00718-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/5d21e8d7198f/molecules-27-00718-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/6d4b76a084da/molecules-27-00718-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/7756242a6316/molecules-27-00718-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/28b1c75b9868/molecules-27-00718-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f77/8839270/12040df27cfd/molecules-27-00718-g005.jpg

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本文引用的文献

1
Laser-Induced Hydrogen Generation from Methanol with Graphene Aerogel as the Target.以石墨烯气凝胶为靶材通过激光从甲醇中诱导产氢
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2
Laser induced white lighting of graphene foam.激光诱导石墨烯泡沫发白光。
Sci Rep. 2017 Jan 23;7:41281. doi: 10.1038/srep41281.
3
Electrochemically assisted microbial production of hydrogen from acetate.电化学辅助微生物从乙酸盐中生产氢气。
Environ Sci Technol. 2005 Jun 1;39(11):4317-20. doi: 10.1021/es050244p.