Nduka David O, Olawuyi Babatunde J, Joshua Opeyemi O, Omuh Ignatius O
Department of Building Technology, College of Science and Technology, Covenant University, Ota 112233, Nigeria.
Department of Building, School of Environmental Technology, Federal University of Technology, Minna 920211, Nigeria.
Gels. 2022 Jan 28;8(2):85. doi: 10.3390/gels8020085.
Supplementary cementitious materials (SCMs) have been widely used to enhance both the microscopic and macroscopic properties of the Portland cement (PC)-SCM composite matrix. Few studies have been undertaken to establish the gel/space ratio of meta-illite calcined clay (MCC) and rice husk ash (RHA)-based high-performance concrete (HPC) mortar. This experimental paper describes a conventional degree of hydration (non-evaporable water) and porosity routes of establishing a link amid the gel/space ratio and compressive strength of a sieved mortar from Class 1 (50-75 MPa) HPC at an early age. Using the non-evaporable water method, this paper predicted the gel/space ratio of the hardened MCC/RHA-based HPC mortars and curved fitted into Powers' exponent equation. The results from this study revealed that MCC or RHA additions (5-30% by weight of PC) to the PC-SCM matrix led to a moderate decline in the compressive strength of the low water-binder ratio (W/B) HPC mortar. The modification aimed at void volume (superabsorbent polymers, SAP, and air) applying Bolomey's formula and Powers' gel/space ratio developed a suitable fitting into the Powers' model. This experimental procedure shows feasibility to predict the MCC and RHA outcome on the compressive strength of HPC.
辅助胶凝材料(SCMs)已被广泛用于改善波特兰水泥(PC)-SCM复合基体的微观和宏观性能。很少有研究致力于确定基于偏高岭土煅烧粘土(MCC)和稻壳灰(RHA)的高性能混凝土(HPC)砂浆的凝胶/空间比。这篇实验论文描述了一种常规的水化程度(非蒸发水)和孔隙率途径,用于在早期建立1类(50-75MPa)HPC筛分砂浆的凝胶/空间比与抗压强度之间的联系。采用非蒸发水法,本文预测了硬化的基于MCC/RHA的HPC砂浆的凝胶/空间比,并将其曲线拟合到鲍尔斯指数方程中。该研究结果表明,向PC-SCM基体中添加MCC或RHA(占PC重量的5-30%)会导致低水胶比(W/B)HPC砂浆的抗压强度适度下降。采用博洛米公式和鲍尔斯凝胶/空间比对孔隙体积(高吸水性聚合物、SAP和空气)进行改性,使其与鲍尔斯模型具有良好的拟合度。该实验程序表明,预测MCC和RHA对HPC抗压强度的影响是可行的。