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具有分级孔结构的Ti-40Al-10Nb-10Cr多孔微滤膜用于从高温烟气中捕集颗粒物

Ti-40Al-10Nb-10Cr Porous Microfiltration Membrane with Hierarchical Pore Structure for Particulate Matter Capturing from High-Temperature Flue Gas.

作者信息

Gui Wanyuan, Shi Zhenjing, Zhang Yin, Liang Yongfeng, Qin Jingyan, Wang Yanli, Lin Junpin, Luan Benli

机构信息

National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China.

State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China.

出版信息

Membranes (Basel). 2022 Jan 18;12(2):104. doi: 10.3390/membranes12020104.

Abstract

TiAl-based porous microfiltration membranes are expected to be the next-generation filtration materials for potential applications in high-temperature flue gas separation in corrosive environments. Unfortunately, the insufficient high-temperature oxidation resistance severely limits their industrial applications. To tackle this issue, a Ti-40Al-10Nb-10Cr porous alloy was fabricated for highly effective high-temperature flue gas purification. Benefited from microstructural changes and the formation of two new phases, the Ti-40Al-10Nb-10Cr porous alloy demonstrated favorable high-temperature anti-oxidation performance with the incorporation of Nb and Cr high-temperature alloying elements. By the separation of a simulated high-temperature flue gas, we achieved an ultra-high PM-removal efficiency (62.242% for PM and 98.563% for PM). These features, combined with our experimental design strategy, provide a new insight into designing high-temperature TiAl-based porous materials with enhanced performance and durability.

摘要

基于TiAl的多孔微滤膜有望成为下一代过滤材料,在腐蚀性环境中的高温烟气分离方面具有潜在应用价值。不幸的是,其不足的高温抗氧化性严重限制了它们的工业应用。为解决这一问题,制备了一种Ti-40Al-10Nb-10Cr多孔合金用于高效高温烟气净化。受益于微观结构变化和两个新相的形成,Ti-40Al-10Nb-10Cr多孔合金通过加入Nb和Cr高温合金元素展现出良好的高温抗氧化性能。通过对模拟高温烟气的分离,我们实现了超高的颗粒物去除效率(对PM2.5的去除效率为62.242%,对PM10的去除效率为98.563%)。这些特性,结合我们的实验设计策略,为设计具有更高性能和耐久性的高温TiAl基多孔材料提供了新的见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47dd/8874596/08dfa1d4b6f4/membranes-12-00104-g001.jpg

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