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使用高钙粉煤灰(HCFA)和粒化高炉矿渣(GGBS)组合对常温固化单组分碱激发胶凝材料进行的实验研究。

Experimental Investigation on Ambient-Cured One-Part Alkali-Activated Binders Using Combined High-Calcium Fly Ash (HCFA) and Ground Granulated Blast Furnace Slag (GGBS).

作者信息

Teo Wee, Shirai Kazutaka, Lim Jee Hock, Jack Lynne B, Nikbakht Ehsan

机构信息

School of Energy, Geoscience, Infrastructure and Society (EGIS), Heriot Watt University Malaysia, Putrajaya 62200, Malaysia.

Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan.

出版信息

Materials (Basel). 2022 Feb 21;15(4):1612. doi: 10.3390/ma15041612.

DOI:10.3390/ma15041612
PMID:35208154
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8876491/
Abstract

The challenges of handling user-hostile alkaline solutions in the conventional alkali-activated binders (AAB) have initiated the development of "just add water" or one-part solid-based AAB systems. This paper aims to present a preliminary investigation on the development of one-part ambient-cured alkali-activated binders produced by synthesising high-calcium fly ash (HCFA) and ground granulated blast furnace slag (GGBS) using sodium metasilicate anhydrous. Three test series were conducted in this study to investigate the effects of GGBS/binder, activator/binder and water/binder ratios on the fresh and hardened properties of the one-part synthesis AAB system. It was found that the SiO/AlO molar ratio plays an important role in the attainment of compressive strength and limits the amounts of solid activators effective in contributing to the alkali-activation reaction process. The optimum SiO/AlO molar ratio was found between 3.20 and 3.30. The test results revealed that the optimum proportion between HCFA and GGBS was discovered at a GGBS/binder ratio of 0.50. The optimum activator/binder ratio was between 0.08 and 0.12, and it is recommended that the water/binder ratio should not exceed 0.50. This study demonstrated the potential of the one-part synthesis method in the production of alkali-activated binder for practical structural applications.

摘要

在传统的碱激发胶凝材料(AAB)中处理对用户不友好的碱性溶液所面临的挑战,引发了“只需加水”或单组分固体基AAB体系的开发。本文旨在对使用无水偏硅酸钠合成高钙粉煤灰(HCFA)和磨细粒化高炉矿渣(GGBS)制备的单组分常温养护碱激发胶凝材料的开发进行初步研究。本研究进行了三个试验系列,以研究GGBS/胶凝材料、激发剂/胶凝材料和水/胶凝材料的比例对单组分合成AAB体系的新拌性能和硬化性能的影响。结果发现,SiO/AlO摩尔比在获得抗压强度方面起着重要作用,并限制了有效促进碱激发反应过程的固体激发剂的用量。最佳SiO/AlO摩尔比在3.20至3.30之间。试验结果表明,当GGBS/胶凝材料比为0.50时,发现了HCFA和GGBS之间的最佳比例。最佳激发剂/胶凝材料比在0.08至0.12之间,建议水/胶凝材料比不应超过0.50。本研究证明了单组分合成方法在生产用于实际结构应用的碱激发胶凝材料方面的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/c0f8b25632d6/materials-15-01612-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/d663a5d1c121/materials-15-01612-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/f129ec113a58/materials-15-01612-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/64ad3f926b2c/materials-15-01612-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/5f97eca81c6d/materials-15-01612-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/ac52c5129d1b/materials-15-01612-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/032cac0cb10e/materials-15-01612-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/c0f8b25632d6/materials-15-01612-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/d663a5d1c121/materials-15-01612-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/f129ec113a58/materials-15-01612-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/64ad3f926b2c/materials-15-01612-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/5f97eca81c6d/materials-15-01612-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/ac52c5129d1b/materials-15-01612-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/032cac0cb10e/materials-15-01612-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/95c4/8876491/c0f8b25632d6/materials-15-01612-g008.jpg

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本文引用的文献

1
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Materials (Basel). 2019 Dec 20;13(1):59. doi: 10.3390/ma13010059.
工业副产品无水泥材料在蒸汽养护预制混凝土制品中的应用试验研究
Materials (Basel). 2022 Oct 30;15(21):7624. doi: 10.3390/ma15217624.