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不同纺丝方法制备的碳纳米管纱线的结构、电学和力学性能的综合表征

Comprehensive Characterization of Structural, Electrical, and Mechanical Properties of Carbon Nanotube Yarns Produced by Various Spinning Methods.

作者信息

Watanabe Takayuki, Yamazaki Satoshi, Yamashita Satoshi, Inaba Takumi, Muroga Shun, Morimoto Takahiro, Kobashi Kazufumi, Okazaki Toshiya

机构信息

CNT-Application Research Center, National Institute of Advanced Industrial Science and Technology, Tsukuba 305-8565, Japan.

Research Association of High-Throughput Design and Development for Advanced Functional Materials (ADMAT), Tsukuba 305-8565, Japan.

出版信息

Nanomaterials (Basel). 2022 Feb 10;12(4):593. doi: 10.3390/nano12040593.

Abstract

A comprehensive characterization of various carbon nanotube (CNT) yarns provides insight for producing high-performance CNT yarns as well as a useful guide to select the proper yarn for a specific application. Herein we systematically investigate the correlations between the physical properties of six CNT yarns produced by three spinning methods, and their structures and the properties of the constituent CNTs. The electrical conductivity increases in all yarns regardless of the spinning method as the effective length of the constituent CNTs and the density of the yarns increase. On the other hand, the tensile strength shows a much stronger dependence on the packing density of the yarns than the CNT effective length, indicating the relative importance of the interfacial interaction. The contribution of each physical parameter to the yarn properties are quantitatively analyzed by partial least square regression.

摘要

对各种碳纳米管(CNT)纱线进行全面表征,有助于深入了解高性能CNT纱线的生产,也为特定应用选择合适的纱线提供了有用的指导。在此,我们系统地研究了通过三种纺丝方法生产的六种CNT纱线的物理性能、结构以及组成碳纳米管的性能之间的相关性。无论采用何种纺丝方法,随着组成碳纳米管的有效长度和纱线密度的增加,所有纱线的电导率都会提高。另一方面,拉伸强度对纱线堆积密度的依赖性比对碳纳米管有效长度的依赖性更强,这表明界面相互作用的相对重要性。通过偏最小二乘回归定量分析了各物理参数对纱线性能的贡献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dfa8/8880327/2552a3e8d6d6/nanomaterials-12-00593-sch001.jpg

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