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纳米氧化锌增强聚醚醚砜纳滤膜对有害金属颗粒截留的影响

Impact of nano-ZnO consolidated poly (ether ether sulfone) nano filtration membrane for evacuation of hazardous metal particles.

作者信息

Maheswari Purushothaman, Mohan Doraiswamy Raju, Krishnan Adhikesavan Hari, Sivaramakrishnan Ramachandran, Pugazhendhi Arivalagan

机构信息

Department of Chemistry, SRM Valliammai Engineering College, Katankulathur, Chennai, 603203, Tamil Nadu, India.

Membrane Laboratory, Department of Chemical Engineering, Anna University, Chennai, 600025, Tamil Nadu, India.

出版信息

Chemosphere. 2022 Jun;297:134024. doi: 10.1016/j.chemosphere.2022.134024. Epub 2022 Feb 25.

Abstract

Industrial wastewater contains heavy metals, colors, dyes, cyanides, and natural manufactured compounds are expanding around the world. It prompts extreme water shortage just as water quality issues. With enhancing worldwide interest for clean and reestablish water for human utilization. Wastewater treatment with membrane innovation is arising as a main cycle to address the issues. In this current work, we have found the expulsion of dangerous metal particles utilizing a nano-ZnO (0.5 wt%) incorporated poly (ether ether sulfone) (PEES) nanofiltration membrane. The created membranes were reviewed by ATR-FTIR, AFM, SEM investigations, XRD, contact angle estimation, mechanical properties, pure water flux, porosity and molecular weight cut-off, arsenic, fluoride, and nitrate rejection studies were illustrated. Because of the hydrophilic nature of ZnO, the resultant membranes had better hydrophilicity than PEES membranes based on porosity, water content, surface chemistry, membrane morphology, and contact angle data. The Nano-ZnO incorporated membrane demonstrated a superior quality execution contrasted with neat PEES membrane. We discovered that the rejection of As(III) and As (V) were > 85% and > 98% separately, and an expanded permeability of 559.28 ± 2 Lm h and 297.95 ± 2 Lm h individually was seen at pH 10. Fluoride and nitrate particles additionally indicated the most extreme expulsion efficiencies were > 89% and > 75% separately. The prepared membrane samples were incubated in water (40 °C) and sodium hypochlorite solution (active chlorine concentration 400 mg/L) for up to 10 days to determine the stability of polymer membrane matrix. The general outcomes inferred that the nano-ZnO incorporated PEES membrane gave remarkable result to eliminate dangerous metal ions with moderate permeability.

摘要

工业废水中含有重金属、色素、染料、氰化物,并且世界各地天然生成的化合物正在不断增加。这不仅导致了严重的水资源短缺,还引发了水质问题。随着全球对清洁和再生水用于人类使用的需求不断增加,利用膜技术进行废水处理正成为解决这些问题的主要方法。在当前这项工作中,我们发现了利用掺入纳米氧化锌(0.5 wt%)的聚(醚醚砜)(PEES)纳滤膜去除有害金属离子的方法。通过衰减全反射傅里叶变换红外光谱(ATR-FTIR)、原子力显微镜(AFM)、扫描电子显微镜(SEM)研究、X射线衍射(XRD)、接触角测量、机械性能、纯水通量、孔隙率和截留分子量、砷、氟化物和硝酸盐截留率研究等对制备的膜进行了表征。由于氧化锌的亲水性,基于孔隙率、含水量、表面化学、膜形态和接触角数据,所得膜比PEES膜具有更好的亲水性。与纯PEES膜相比,掺入纳米氧化锌的膜表现出卓越的性能。我们发现,在pH值为10时,对As(III)和As(V)的截留率分别>85%和>98%,并且分别观察到渗透通量增加至559.28±2 Lm h和297.95±2 Lm h。氟化物和硝酸盐离子也分别显示出最高截留效率>89%和>75%。将制备的膜样品在水(40°C)和次氯酸钠溶液(有效氯浓度400 mg/L)中孵育长达10天,以确定聚合物膜基质的稳定性。总体结果表明,掺入纳米氧化锌的PEES膜在具有适度渗透通量的情况下,对于去除有害金属离子具有显著效果。

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